Formation of metallaboratranes: The missing link. the first iridaboratranes, [IrH(CO)(PPh3){K3-B,S,S′-B(mt) 2R}](Ir→B) (mt = methimazolyl, R = mt, H)

Ian R. Crossley, Anthony F. Hill*, Anthony C. Willis

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    114 Citations (Scopus)

    Abstract

    The reaction of Vaska's complex with 1 equiv of Na[HB(mt)3] or Na[H2(mt)2] (mt = methimazolyl) affords the iridaboratranes [IrH(CO)(PPh3){k3-B,S,S′-B(mt) 2R}](IrI→B) (R = mt, H), the first examples of metallaboratranes in which the transannular metal-boron bond is supported by only two methimazolyl buttresses.

    Original languageEnglish
    Pages (from-to)1062-1064
    Number of pages3
    JournalOrganometallics
    Volume24
    Issue number6
    DOIs
    Publication statusPublished - 14 Mar 2005

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