Formation of metallaboratranes: The missing link. the first iridaboratranes, [IrH(CO)(PPh3){K3-B,S,S′-B(mt) 2R}](Ir→B) (mt = methimazolyl, R = mt, H)

Ian R. Crossley; Anthony F. Hill; Anthony C. Willis

doi:10.1021/om040128f

Formation of metallaboratranes: The missing link. the first iridaboratranes, [IrH(CO)(PPh₃){K³-B,S,S′-B(mt) ₂R}](Ir→B) (mt = methimazolyl, R = mt, H)

Ian R. Crossley, Anthony F. Hill^*, Anthony C. Willis

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

117 Citations (Scopus)

Abstract

The reaction of Vaska's complex with 1 equiv of Na[HB(mt)₃] or Na[H₂(mt)₂] (mt = methimazolyl) affords the iridaboratranes [IrH(CO)(PPh₃){k³-B,S,S′-B(mt) ₂R}](Ir^I→B) (R = mt, H), the first examples of metallaboratranes in which the transannular metal-boron bond is supported by only two methimazolyl buttresses.

Original language	English
Pages (from-to)	1062-1064
Number of pages	3
Journal	Organometallics
Volume	24
Issue number	6
DOIs	https://doi.org/10.1021/om040128f
Publication status	Published - 14 Mar 2005

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title = "Formation of metallaboratranes: The missing link. the first iridaboratranes, [IrH(CO)(PPh3){K3-B,S,S′-B(mt) 2R}](Ir→B) (mt = methimazolyl, R = mt, H)",

abstract = "The reaction of Vaska's complex with 1 equiv of Na[HB(mt)3] or Na[H2(mt)2] (mt = methimazolyl) affords the iridaboratranes [IrH(CO)(PPh3){k3-B,S,S′-B(mt) 2R}](IrI→B) (R = mt, H), the first examples of metallaboratranes in which the transannular metal-boron bond is supported by only two methimazolyl buttresses.",

author = "Crossley, {Ian R.} and Hill, {Anthony F.} and Willis, {Anthony C.}",

year = "2005",

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T2 - The missing link. the first iridaboratranes, [IrH(CO)(PPh3){K3-B,S,S′-B(mt) 2R}](Ir→B) (mt = methimazolyl, R = mt, H)

AU - Crossley, Ian R.

AU - Hill, Anthony F.

AU - Willis, Anthony C.

PY - 2005/3/14

Y1 - 2005/3/14

N2 - The reaction of Vaska's complex with 1 equiv of Na[HB(mt)3] or Na[H2(mt)2] (mt = methimazolyl) affords the iridaboratranes [IrH(CO)(PPh3){k3-B,S,S′-B(mt) 2R}](IrI→B) (R = mt, H), the first examples of metallaboratranes in which the transannular metal-boron bond is supported by only two methimazolyl buttresses.

AB - The reaction of Vaska's complex with 1 equiv of Na[HB(mt)3] or Na[H2(mt)2] (mt = methimazolyl) affords the iridaboratranes [IrH(CO)(PPh3){k3-B,S,S′-B(mt) 2R}](IrI→B) (R = mt, H), the first examples of metallaboratranes in which the transannular metal-boron bond is supported by only two methimazolyl buttresses.

UR - http://www.scopus.com/inward/record.url?scp=15944403570&partnerID=8YFLogxK

U2 - 10.1021/om040128f

DO - 10.1021/om040128f

M3 - Article

SN - 0276-7333

VL - 24

SP - 1062

EP - 1064

JO - Organometallics

JF - Organometallics

IS - 6

ER -

Formation of metallaboratranes: The missing link. the first iridaboratranes, [IrH(CO)(PPh3){K3-B,S,S′-B(mt) 2R}](Ir→B) (mt = methimazolyl, R = mt, H)

Abstract

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Formation of metallaboratranes: The missing link. the first iridaboratranes, [IrH(CO)(PPh₃){K³-B,S,S′-B(mt) ₂R}](Ir→B) (mt = methimazolyl, R = mt, H)