gem-dihalocyclopropanes as building blocks in natural product synthesis

Rebecca M. Taylor

doi:10.1071/CH02223

gem-dihalocyclopropanes as building blocks in natural product synthesis

Rebecca M. Taylor^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

gem-Dihalocyclopropanes are readily prepared by dihalocarbene addition to the corresponding alkene. These compounds have considerable potential as building blocks in chemical synthesis, especially of natural products. Particular applications include the intramolecular trapping of allylic cations by hateroatom-centered nucleophiles and intermolecular trapping of allylic cations by carbon-centered nucleophiles.

Original language	English
Pages (from-to)	631
Number of pages	1
Journal	Australian Journal of Chemistry
Volume	56
Issue number	6
DOIs	https://doi.org/10.1071/CH02223
Publication status	Published - 2003

Access to Document

10.1071/CH02223

Cite this

@article{43681606f0144c908b3111467edef5b2,

title = "gem-dihalocyclopropanes as building blocks in natural product synthesis",

abstract = "gem-Dihalocyclopropanes are readily prepared by dihalocarbene addition to the corresponding alkene. These compounds have considerable potential as building blocks in chemical synthesis, especially of natural products. Particular applications include the intramolecular trapping of allylic cations by hateroatom-centered nucleophiles and intermolecular trapping of allylic cations by carbon-centered nucleophiles.",

author = "Taylor, {Rebecca M.}",

year = "2003",

doi = "10.1071/CH02223",

language = "English",

volume = "56",

pages = "631",

journal = "Australian Journal of Chemistry",

issn = "0004-9425",

publisher = "CSIRO",

number = "6",

}

TY - JOUR

T1 - gem-dihalocyclopropanes as building blocks in natural product synthesis

AU - Taylor, Rebecca M.

PY - 2003

Y1 - 2003

N2 - gem-Dihalocyclopropanes are readily prepared by dihalocarbene addition to the corresponding alkene. These compounds have considerable potential as building blocks in chemical synthesis, especially of natural products. Particular applications include the intramolecular trapping of allylic cations by hateroatom-centered nucleophiles and intermolecular trapping of allylic cations by carbon-centered nucleophiles.

AB - gem-Dihalocyclopropanes are readily prepared by dihalocarbene addition to the corresponding alkene. These compounds have considerable potential as building blocks in chemical synthesis, especially of natural products. Particular applications include the intramolecular trapping of allylic cations by hateroatom-centered nucleophiles and intermolecular trapping of allylic cations by carbon-centered nucleophiles.

UR - http://www.scopus.com/inward/record.url?scp=0345055601&partnerID=8YFLogxK

U2 - 10.1071/CH02223

DO - 10.1071/CH02223

M3 - Article

SN - 0004-9425

VL - 56

SP - 631

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 6

ER -

gem-dihalocyclopropanes as building blocks in natural product synthesis

Abstract

Access to Document

Other files and links

Fingerprint

Cite this