TY - JOUR
T1 - Geochemistry and Geochronology of A-Type Intermediate-Felsic Rocks in NW Himalaya, Pakistan
T2 - Implications for Petrogenesis and Tectonic Evolution of Northern Gondwana
AU - Khan, Musa
AU - Li, Huan
AU - Algeo, Thomas J.
AU - Khan, Asad
AU - Förster, Michael W.
AU - Ullah, Zaheen
N1 - Publisher Copyright:
© 2025 The Author(s). Geochemistry, Geophysics, Geosystems published by Wiley Periodicals LLC on behalf of American Geophysical Union.
PY - 2025/1
Y1 - 2025/1
N2 - Igneous intrusives in northern Pakistan can provide valuable insights into pre-Himalayan metaluminous to peraluminous magmatism along the northern boundary of the supercontinent Gondwana and its potential tectonic significance. This study generates new geochronologic, petrographic and geochemical data for intermediate (monzonite, syenite, and foid syenite) and felsic (granite and quartz monzonite) rocks within the NW Himalayan region of Pakistan. Both the intermediate and felsic rocks have values of A/NK > 1.1, implying a metaluminous to peraluminous composition, and are distinguished by high FeOT/(MgO + FeOT) (0.81–1.0), high 10,000 × Ga/Al ratio (2.1–5.1), elevated Nb + Zr + Y + Ce contents (122–1,204 ppm), and negative anomalies of P and Ti, consistent with aluminous A-type magmatic affinity. These rocks are classified as A1-type, which is linked to anorogenic intraplate extensional setting. Both rock groups yield high calculated average whole-rock Zr saturation temperatures (i.e., TZr; 790–823°C), which suggests formation from high-temperature magmas. Whole-rock geochemistry, including variable (87Sr/86Sr)i values (0.7034–0.7086), positive εNd(t) (+0.1 to +3.9), high Pb isotopic values (that is, (206Pb/204Pb)i = 18.68 to 19.31, (207Pb/204Pb)i = 15.64 to 15.74, and (208Pb/204Pb)i = 38.93 to 39.78), and variation in zircon εHf(t) values (+0.8 to +7.0), indicates diverse magma sources for the intermediate-felsic rocks and provide evidence of partial melting of metasomatized lithospheric mantle, producing a primary magma of foid to quartz syenitic composition. Subsequently, this magma was responsible for the partial melting of the overlying juvenile crust, producing granitic, quartz monzonitic and monzonitic magmas. During the magma evolution process of these rocks, this process was primarily determined by partial melting that followed fractionation of K-feldspar, ilmenite and apatite. TDM2 ages indicate that the parent materials of intermediate-felsic rocks were generated during the Mesoproterozoic-Neoproterozoic. LA-ICP–MS U-Pb dating of magmatic zircons documents their formation in the Late Paleozoic at ∼278-268 Ma. The intermediate-felsic rocks are correlatable with alkaline igneous rocks of the Peshawar Plain, which record the breakup of the supercontinent Gondwana and the subsequent opening of Neo-Tethys during a Late Paleozoic rifting event. The nepheline syenite records a younger episode during the Cenozoic (37 Ma), corresponding to the collision of the Indian-Eurasian tectonic plates.
AB - Igneous intrusives in northern Pakistan can provide valuable insights into pre-Himalayan metaluminous to peraluminous magmatism along the northern boundary of the supercontinent Gondwana and its potential tectonic significance. This study generates new geochronologic, petrographic and geochemical data for intermediate (monzonite, syenite, and foid syenite) and felsic (granite and quartz monzonite) rocks within the NW Himalayan region of Pakistan. Both the intermediate and felsic rocks have values of A/NK > 1.1, implying a metaluminous to peraluminous composition, and are distinguished by high FeOT/(MgO + FeOT) (0.81–1.0), high 10,000 × Ga/Al ratio (2.1–5.1), elevated Nb + Zr + Y + Ce contents (122–1,204 ppm), and negative anomalies of P and Ti, consistent with aluminous A-type magmatic affinity. These rocks are classified as A1-type, which is linked to anorogenic intraplate extensional setting. Both rock groups yield high calculated average whole-rock Zr saturation temperatures (i.e., TZr; 790–823°C), which suggests formation from high-temperature magmas. Whole-rock geochemistry, including variable (87Sr/86Sr)i values (0.7034–0.7086), positive εNd(t) (+0.1 to +3.9), high Pb isotopic values (that is, (206Pb/204Pb)i = 18.68 to 19.31, (207Pb/204Pb)i = 15.64 to 15.74, and (208Pb/204Pb)i = 38.93 to 39.78), and variation in zircon εHf(t) values (+0.8 to +7.0), indicates diverse magma sources for the intermediate-felsic rocks and provide evidence of partial melting of metasomatized lithospheric mantle, producing a primary magma of foid to quartz syenitic composition. Subsequently, this magma was responsible for the partial melting of the overlying juvenile crust, producing granitic, quartz monzonitic and monzonitic magmas. During the magma evolution process of these rocks, this process was primarily determined by partial melting that followed fractionation of K-feldspar, ilmenite and apatite. TDM2 ages indicate that the parent materials of intermediate-felsic rocks were generated during the Mesoproterozoic-Neoproterozoic. LA-ICP–MS U-Pb dating of magmatic zircons documents their formation in the Late Paleozoic at ∼278-268 Ma. The intermediate-felsic rocks are correlatable with alkaline igneous rocks of the Peshawar Plain, which record the breakup of the supercontinent Gondwana and the subsequent opening of Neo-Tethys during a Late Paleozoic rifting event. The nepheline syenite records a younger episode during the Cenozoic (37 Ma), corresponding to the collision of the Indian-Eurasian tectonic plates.
KW - Ambela Granitic Complex
KW - Indian Plate
KW - juvenile crust
KW - metasomatism
KW - monzonite
KW - syenite
UR - http://www.scopus.com/inward/record.url?scp=85215067990&partnerID=8YFLogxK
U2 - 10.1029/2024GC011802
DO - 10.1029/2024GC011802
M3 - Article
AN - SCOPUS:85215067990
SN - 1525-2027
VL - 26
JO - Geochemistry, Geophysics, Geosystems
JF - Geochemistry, Geophysics, Geosystems
IS - 1
M1 - e2024GC011802
ER -