Graphene with reciprocating carbon chains for long-term corrosion protection

Duosheng Li; Wei Zou; Shengli Song; Yin Ye; Zhiguo Ye; Qing H. Qin; Dunwen Zuo; Wenzhuang Lu

doi:10.1016/j.ceramint.2021.01.068

Graphene with reciprocating carbon chains for long-term corrosion protection

Duosheng Li^*, Wei Zou, Shengli Song^*, Yin Ye, Zhiguo Ye, Qing H. Qin, Dunwen Zuo, Wenzhuang Lu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Graphene coatings generally cannot provide effective long-time protection for metal substrates. In this study, we developed a novel graphene coating that forms reciprocating carbon chains at the defects of graphene (FRCCDG). The FRCCDG coating deposited on Ni substrate exhibits excellent corrosion resistance over extended durations. Compared with conventional graphene coatings, FRCCDG coatings have lower defect density and higher crystallinity. They form a barrier at the defects of the graphene, thereby hindering the penetration of corrosive elements and improving the ability of graphene to inhibit corrosion. When exposed to air for a period of seven months, the degree of oxidation of FRCCDG-coated Ni foil is lower than that of uncoated substrate. This confirms that the FRCCDG coating has long-lasting corrosion and oxidation resistance.

Original language	English
Pages (from-to)	12205-12210
Number of pages	6
Journal	Ceramics International
Volume	47
Issue number	9
DOIs	https://doi.org/10.1016/j.ceramint.2021.01.068
Publication status	Published - 1 May 2021

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10.1016/j.ceramint.2021.01.068

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title = "Graphene with reciprocating carbon chains for long-term corrosion protection",

abstract = "Graphene coatings generally cannot provide effective long-time protection for metal substrates. In this study, we developed a novel graphene coating that forms reciprocating carbon chains at the defects of graphene (FRCCDG). The FRCCDG coating deposited on Ni substrate exhibits excellent corrosion resistance over extended durations. Compared with conventional graphene coatings, FRCCDG coatings have lower defect density and higher crystallinity. They form a barrier at the defects of the graphene, thereby hindering the penetration of corrosive elements and improving the ability of graphene to inhibit corrosion. When exposed to air for a period of seven months, the degree of oxidation of FRCCDG-coated Ni foil is lower than that of uncoated substrate. This confirms that the FRCCDG coating has long-lasting corrosion and oxidation resistance.",

keywords = "Anti-Corrosion coating, Graphene, Oxidation, Reciprocating carbon chain, Sodium dodecyl benzene sulfonate",

author = "Duosheng Li and Wei Zou and Shengli Song and Yin Ye and Zhiguo Ye and Qin, {Qing H.} and Dunwen Zuo and Wenzhuang Lu",

note = "Publisher Copyright: {\textcopyright} 2021 Elsevier Ltd and Techna Group S.r.l.",

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T1 - Graphene with reciprocating carbon chains for long-term corrosion protection

AU - Li, Duosheng

AU - Zou, Wei

AU - Song, Shengli

AU - Ye, Yin

AU - Ye, Zhiguo

AU - Qin, Qing H.

AU - Zuo, Dunwen

AU - Lu, Wenzhuang

PY - 2021/5/1

Y1 - 2021/5/1

N2 - Graphene coatings generally cannot provide effective long-time protection for metal substrates. In this study, we developed a novel graphene coating that forms reciprocating carbon chains at the defects of graphene (FRCCDG). The FRCCDG coating deposited on Ni substrate exhibits excellent corrosion resistance over extended durations. Compared with conventional graphene coatings, FRCCDG coatings have lower defect density and higher crystallinity. They form a barrier at the defects of the graphene, thereby hindering the penetration of corrosive elements and improving the ability of graphene to inhibit corrosion. When exposed to air for a period of seven months, the degree of oxidation of FRCCDG-coated Ni foil is lower than that of uncoated substrate. This confirms that the FRCCDG coating has long-lasting corrosion and oxidation resistance.

AB - Graphene coatings generally cannot provide effective long-time protection for metal substrates. In this study, we developed a novel graphene coating that forms reciprocating carbon chains at the defects of graphene (FRCCDG). The FRCCDG coating deposited on Ni substrate exhibits excellent corrosion resistance over extended durations. Compared with conventional graphene coatings, FRCCDG coatings have lower defect density and higher crystallinity. They form a barrier at the defects of the graphene, thereby hindering the penetration of corrosive elements and improving the ability of graphene to inhibit corrosion. When exposed to air for a period of seven months, the degree of oxidation of FRCCDG-coated Ni foil is lower than that of uncoated substrate. This confirms that the FRCCDG coating has long-lasting corrosion and oxidation resistance.

KW - Anti-Corrosion coating

KW - Graphene

KW - Oxidation

KW - Reciprocating carbon chain

KW - Sodium dodecyl benzene sulfonate

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U2 - 10.1016/j.ceramint.2021.01.068

DO - 10.1016/j.ceramint.2021.01.068

M3 - Article

SN - 0272-8842

VL - 47

SP - 12205

EP - 12210

JO - Ceramics International

JF - Ceramics International

IS - 9

ER -

Graphene with reciprocating carbon chains for long-term corrosion protection

Abstract

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