Group 8 metal alkynyl complexes for nonlinear optics

Guillaume Grelaud; Marie P. Cifuentes; Frédéric Paul; Mark G. Humphrey

doi:10.1016/j.jorganchem.2013.10.008

Group 8 metal alkynyl complexes for nonlinear optics

Guillaume Grelaud, Marie P. Cifuentes, Frédéric Paul, Mark G. Humphrey^*

^*Corresponding author for this work

Research output: Contribution to journal › Review article › peer-review

76 Citations (Scopus)

Abstract

Studies of the nonlinear optical (NLO) properties of Group 8 metal alkynyl complexes are summarized, with particular focus on results since 2003; structureeNLO property relationships are developed, optical nonlinearities of multipolar alkynyl complexes are described, and switching of the NLO response of molecules and molecular materials derived from Group 8 metal alkynyl complexes is discussed.

Original language	English
Pages (from-to)	181-200
Number of pages	20
Journal	Journal of Organometallic Chemistry
Volume	751
DOIs	https://doi.org/10.1016/j.jorganchem.2013.10.008
Publication status	Published - 1 Feb 2014

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10.1016/j.jorganchem.2013.10.008

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abstract = "Studies of the nonlinear optical (NLO) properties of Group 8 metal alkynyl complexes are summarized, with particular focus on results since 2003; structureeNLO property relationships are developed, optical nonlinearities of multipolar alkynyl complexes are described, and switching of the NLO response of molecules and molecular materials derived from Group 8 metal alkynyl complexes is discussed.",

keywords = "Acetylide complexes, Alkynyl complexes, Cubic nonlinearities, Hyperpolarizabilities, Nonlinear optics, Quadratic nonlinearities",

author = "Guillaume Grelaud and Cifuentes, {Marie P.} and Fr{\'e}d{\'e}ric Paul and Humphrey, {Mark G.}",

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doi = "10.1016/j.jorganchem.2013.10.008",

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AU - Grelaud, Guillaume

AU - Cifuentes, Marie P.

AU - Paul, Frédéric

AU - Humphrey, Mark G.

PY - 2014/2/1

Y1 - 2014/2/1

N2 - Studies of the nonlinear optical (NLO) properties of Group 8 metal alkynyl complexes are summarized, with particular focus on results since 2003; structureeNLO property relationships are developed, optical nonlinearities of multipolar alkynyl complexes are described, and switching of the NLO response of molecules and molecular materials derived from Group 8 metal alkynyl complexes is discussed.

AB - Studies of the nonlinear optical (NLO) properties of Group 8 metal alkynyl complexes are summarized, with particular focus on results since 2003; structureeNLO property relationships are developed, optical nonlinearities of multipolar alkynyl complexes are described, and switching of the NLO response of molecules and molecular materials derived from Group 8 metal alkynyl complexes is discussed.

KW - Acetylide complexes

KW - Alkynyl complexes

KW - Cubic nonlinearities

KW - Hyperpolarizabilities

KW - Nonlinear optics

KW - Quadratic nonlinearities

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U2 - 10.1016/j.jorganchem.2013.10.008

DO - 10.1016/j.jorganchem.2013.10.008

M3 - Review article

SN - 0022-328X

VL - 751

SP - 181

EP - 200

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Group 8 metal alkynyl complexes for nonlinear optics

Abstract

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