Halogenation of A-frame μ-carbido complexes: A diamagnetic rhodium(ii) carbido complex

Harrison J. Barnett; Anthony F. Hill

doi:10.1039/d0cc02349c

Halogenation of A-frame μ-carbido complexes: A diamagnetic rhodium(ii) carbido complex

Harrison J. Barnett, Anthony F. Hill^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The reaction of [Rh2(μ-C)Cl2(PPh3)4] with 1,1′-bis(diphenylphosphino)ferrocene (dppf) affords the μ-carbido complex [Rh2(μ-C)Cl2(μ-dppf)2] which reacts with PhICl2 to provide a diamagnetic dirhodium(ii) carbido complex [Rh2(μ-C)Cl4(μ-dppf)2].

Original language	English
Pages (from-to)	7738-7740
Number of pages	3
Journal	Chemical Communications
Volume	56
Issue number	56
DOIs	https://doi.org/10.1039/d0cc02349c
Publication status	Published - 18 Jul 2020

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title = "Halogenation of A-frame μ-carbido complexes: A diamagnetic rhodium(ii) carbido complex",

abstract = "The reaction of [Rh2(μ-C)Cl2(PPh3)4] with 1,1′-bis(diphenylphosphino)ferrocene (dppf) affords the μ-carbido complex [Rh2(μ-C)Cl2(μ-dppf)2] which reacts with PhICl2 to provide a diamagnetic dirhodium(ii) carbido complex [Rh2(μ-C)Cl4(μ-dppf)2].",

author = "Barnett, {Harrison J.} and Hill, {Anthony F.}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2020",

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doi = "10.1039/d0cc02349c",

language = "English",

volume = "56",

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journal = "Chemical Communications",

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T1 - Halogenation of A-frame μ-carbido complexes

T2 - A diamagnetic rhodium(ii) carbido complex

AU - Barnett, Harrison J.

AU - Hill, Anthony F.

PY - 2020/7/18

Y1 - 2020/7/18

N2 - The reaction of [Rh2(μ-C)Cl2(PPh3)4] with 1,1′-bis(diphenylphosphino)ferrocene (dppf) affords the μ-carbido complex [Rh2(μ-C)Cl2(μ-dppf)2] which reacts with PhICl2 to provide a diamagnetic dirhodium(ii) carbido complex [Rh2(μ-C)Cl4(μ-dppf)2].

AB - The reaction of [Rh2(μ-C)Cl2(PPh3)4] with 1,1′-bis(diphenylphosphino)ferrocene (dppf) affords the μ-carbido complex [Rh2(μ-C)Cl2(μ-dppf)2] which reacts with PhICl2 to provide a diamagnetic dirhodium(ii) carbido complex [Rh2(μ-C)Cl4(μ-dppf)2].

UR - http://www.scopus.com/inward/record.url?scp=85088180627&partnerID=8YFLogxK

U2 - 10.1039/d0cc02349c

DO - 10.1039/d0cc02349c

M3 - Article

SN - 1359-7345

VL - 56

SP - 7738

EP - 7740

JO - Chemical Communications

JF - Chemical Communications

IS - 56

ER -

Halogenation of A-frame μ-carbido complexes: A diamagnetic rhodium(ii) carbido complex

Abstract

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