Heptacarbonylbis(μ33-η2-diphenylacetylene) -(η5-pentamethylcyclopentadienyl)triiridium-tungsten

Anthony C. Willis; Gulliver T. Dalton; Mark G. Humphrey

doi:10.1107/S1600536804006439

Heptacarbonylbis(μ₃3-η²-diphenylacetylene) -(η⁵-pentamethylcyclopentadienyl)triiridium-tungsten

Anthony C. Willis
, Gulliver T. Dalton
, Mark G. Humphrey^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, [WIr₃(η-C₁₀H ₁₅)(μ₃-η²-C₁₄H ₁₀(CO)₇], is a mixed-metal cluster with a tetrahedral metal core geometry. One diphenylacetylene ligand is μ₃- η²-coordinated to the triiridium face, while the other is μ₃-η²-coordinated to a diiridiumtungsten face. The W atom is ligated by a pentamethylcyclopentadienyl ligand and a terminal carbonyl, and the Ir atoms are each ligated by two terminal carbonyls.

Original language	English
Pages (from-to)	m458-m459
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	4
DOIs	https://doi.org/10.1107/S1600536804006439
Publication status	Published - Apr 2004

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title = "Heptacarbonylbis(μ33-η2-diphenylacetylene) -(η5-pentamethylcyclopentadienyl)triiridium-tungsten",

abstract = "The title compound, [WIr3(η-C10H 15)(μ3-η2-C14H 10(CO)7], is a mixed-metal cluster with a tetrahedral metal core geometry. One diphenylacetylene ligand is μ3- η2-coordinated to the triiridium face, while the other is μ3-η2-coordinated to a diiridiumtungsten face. The W atom is ligated by a pentamethylcyclopentadienyl ligand and a terminal carbonyl, and the Ir atoms are each ligated by two terminal carbonyls.",

author = "Willis, \{Anthony C.\} and Dalton, \{Gulliver T.\} and Humphrey, \{Mark G.\}",

year = "2004",

month = apr,

doi = "10.1107/S1600536804006439",

language = "English",

volume = "60",

pages = "m458--m459",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "4",

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TY - JOUR

T1 - Heptacarbonylbis(μ33-η2-diphenylacetylene) -(η5-pentamethylcyclopentadienyl)triiridium-tungsten

AU - Willis, Anthony C.

AU - Dalton, Gulliver T.

AU - Humphrey, Mark G.

PY - 2004/4

Y1 - 2004/4

N2 - The title compound, [WIr3(η-C10H 15)(μ3-η2-C14H 10(CO)7], is a mixed-metal cluster with a tetrahedral metal core geometry. One diphenylacetylene ligand is μ3- η2-coordinated to the triiridium face, while the other is μ3-η2-coordinated to a diiridiumtungsten face. The W atom is ligated by a pentamethylcyclopentadienyl ligand and a terminal carbonyl, and the Ir atoms are each ligated by two terminal carbonyls.

AB - The title compound, [WIr3(η-C10H 15)(μ3-η2-C14H 10(CO)7], is a mixed-metal cluster with a tetrahedral metal core geometry. One diphenylacetylene ligand is μ3- η2-coordinated to the triiridium face, while the other is μ3-η2-coordinated to a diiridiumtungsten face. The W atom is ligated by a pentamethylcyclopentadienyl ligand and a terminal carbonyl, and the Ir atoms are each ligated by two terminal carbonyls.

UR - https://www.scopus.com/pages/publications/18444396164

U2 - 10.1107/S1600536804006439

DO - 10.1107/S1600536804006439

M3 - Article

SN - 1600-5368

VL - 60

SP - m458-m459

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Heptacarbonylbis(μ₃3-η²-diphenylacetylene) -(η⁵-pentamethylcyclopentadienyl)triiridium-tungsten

Abstract

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