Heterobimetallic μ2-carbido complexes of platinum and tungsten

Anthony F. Hill*, Liam K. Burt

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    12 Citations (Scopus)

    Abstract

    The tungsten-platinum μ-carbido complex [WPt(μ-C)Br(CO)2(PPh3)2(Tp∗)] (Tp∗ = hydrotris(dimethylpyrazol-1-yl)borate) undergoes facile substitution of both bromide and phosphine ligands to afford a diverse library of μ-carbido complexes that includes [WPt(μ-C)Br(CO)2(dppe)(Tp∗)], [WPt(μ-C)(NCMe)(CO)2(PPh3)2(Tp∗)]OTf, [WPt(μ-C)(S2CNEt2)(CO)2(PPh3)(Tp∗)], [WPt(μ-C)(bipy)(CO)2(PPh3)(Tp∗)]PF6, [WPt(μ-C)(phen)(CO)2(PPh3)(Tp∗)]PF6, [WPt(μ-C)(terpy)(CO)2(Tp∗)]PF6, [WPt(μ-C)(CO)2(PPh3)(Bp∗)(Tp∗)], [WPt(μ-C)(CO)2(PPh3)(Tp∗)2] and [WPt(μ-C)(bipy)(CO)2(PPh3)(Bm)(Tp∗)], most of which have been structurally charcaterised.

    Original languageEnglish
    Pages (from-to)8143-8161
    Number of pages19
    JournalDalton Transactions
    Volume49
    Issue number24
    DOIs
    Publication statusPublished - 28 Jun 2020

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