Heterobimetallic C3 Complexes through Silylpropargylidyne Desilylation

Rian D. Dewhurst; Anthony F. Hill; Matthew K. Smith

doi:10.1002/anie.200352693

Heterobimetallic C₃ Complexes through Silylpropargylidyne Desilylation

Rian D. Dewhurst
, Anthony F. Hill^*
, Matthew K. Smith

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

48 Citations (Scopus)

Abstract

Odd compounds: The study of bimetallic complexes spanned by linear carbon chains was mainly restricted to even-numbered chains. The fluorodesilylation of silylated propargylidynes now provides a range of C₃-spanned heterobimetallic complexes based on Ru and either Mo or W (e.g. see picture).

Original language	English
Pages (from-to)	476-478
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	4
DOIs	https://doi.org/10.1002/anie.200352693
Publication status	Published - 16 Jan 2004

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title = "Heterobimetallic C3 Complexes through Silylpropargylidyne Desilylation",

abstract = "Odd compounds: The study of bimetallic complexes spanned by linear carbon chains was mainly restricted to even-numbered chains. The fluorodesilylation of silylated propargylidynes now provides a range of C3-spanned heterobimetallic complexes based on Ru and either Mo or W (e.g. see picture).",

keywords = "Alkynes, Carbynes, Multiple bonds, Ruthenium, Tungsten",

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T1 - Heterobimetallic C3 Complexes through Silylpropargylidyne Desilylation

AU - Dewhurst, Rian D.

AU - Hill, Anthony F.

AU - Smith, Matthew K.

PY - 2004/1/16

Y1 - 2004/1/16

N2 - Odd compounds: The study of bimetallic complexes spanned by linear carbon chains was mainly restricted to even-numbered chains. The fluorodesilylation of silylated propargylidynes now provides a range of C3-spanned heterobimetallic complexes based on Ru and either Mo or W (e.g. see picture).

AB - Odd compounds: The study of bimetallic complexes spanned by linear carbon chains was mainly restricted to even-numbered chains. The fluorodesilylation of silylated propargylidynes now provides a range of C3-spanned heterobimetallic complexes based on Ru and either Mo or W (e.g. see picture).

KW - Alkynes

KW - Carbynes

KW - Multiple bonds

KW - Ruthenium

KW - Tungsten

UR - https://www.scopus.com/pages/publications/0842264226

U2 - 10.1002/anie.200352693

DO - 10.1002/anie.200352693

M3 - Article

SN - 1433-7851

VL - 43

SP - 476

EP - 478

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 4

ER -

Heterobimetallic C₃ Complexes through Silylpropargylidyne Desilylation

Abstract

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