Heterocyclic arsinocarbynes <i>via</i> tandem transmetallation

Benjamin J. Frogley; Anthony F. Hill; Ryan M. Kirk

doi:10.1039/d1cc03015a

Heterocyclic arsinocarbynes <i>via</i> tandem transmetallation

Benjamin J. Frogley
, Anthony F. Hill
, Ryan M. Kirk

The Australian National University

Research output: Contribution to journal › Literature review › peer-review

Abstract

Gold(i)-catalysed tandem transmetallation (Sn -> Au -> As) of the stannylcarbyne [W(equivalent to(CSnBu3)-Bu-n)(CO)(2)(Tp*)] (Tp* = hydrotris-(dimethylpyrazolyl)borate) with haloarsines gives direct access to a range of novel arsinocarbyne complexes, LnM equivalent to CAsR2, including unusual heterocyclic phenarsazininyl and arsolyl examples.

Original language	English
Pages (from-to)	8770-8773
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	70
Early online date	Jul 2021
DOIs	https://doi.org/10.1039/d1cc03015a
Publication status	Published - 11 Sept 2021

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10.1039/d1cc03015a

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title = "Heterocyclic arsinocarbynes via tandem transmetallation",

abstract = "Gold(i)-catalysed tandem transmetallation (Sn -> Au -> As) of the stannylcarbyne [W(equivalent to(CSnBu3)-Bu-n)(CO)(2)(Tp*)] (Tp* = hydrotris-(dimethylpyrazolyl)borate) with haloarsines gives direct access to a range of novel arsinocarbyne complexes, LnM equivalent to CAsR2, including unusual heterocyclic phenarsazininyl and arsolyl examples.",

keywords = "Tp-asterisk, Complexes, Carbyne, Mo, Coordination, Aromaticity, Arsaalkenes, Carbido, Carbon, Bi",

author = "Frogley, \{Benjamin J.\} and Hill, \{Anthony F.\} and Kirk, \{Ryan M.\}",

year = "2021",

month = sep,

day = "11",

doi = "10.1039/d1cc03015a",

language = "English",

volume = "57",

pages = "8770--8773",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "70",

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TY - JOUR

T1 - Heterocyclic arsinocarbynes via tandem transmetallation

AU - Frogley, Benjamin J.

AU - Hill, Anthony F.

AU - Kirk, Ryan M.

PY - 2021/9/11

Y1 - 2021/9/11

N2 - Gold(i)-catalysed tandem transmetallation (Sn -> Au -> As) of the stannylcarbyne [W(equivalent to(CSnBu3)-Bu-n)(CO)(2)(Tp*)] (Tp* = hydrotris-(dimethylpyrazolyl)borate) with haloarsines gives direct access to a range of novel arsinocarbyne complexes, LnM equivalent to CAsR2, including unusual heterocyclic phenarsazininyl and arsolyl examples.

AB - Gold(i)-catalysed tandem transmetallation (Sn -> Au -> As) of the stannylcarbyne [W(equivalent to(CSnBu3)-Bu-n)(CO)(2)(Tp*)] (Tp* = hydrotris-(dimethylpyrazolyl)borate) with haloarsines gives direct access to a range of novel arsinocarbyne complexes, LnM equivalent to CAsR2, including unusual heterocyclic phenarsazininyl and arsolyl examples.

KW - Tp-asterisk

KW - Complexes

KW - Carbyne

KW - Mo

KW - Coordination

KW - Aromaticity

KW - Arsaalkenes

KW - Carbido

KW - Carbon

KW - Bi

UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:000683767100001&DestLinkType=FullRecord&DestApp=WOS_CPL

U2 - 10.1039/d1cc03015a

DO - 10.1039/d1cc03015a

M3 - Literature review

C2 - 34378572

SN - 1359-7345

VL - 57

SP - 8770

EP - 8773

JO - Chemical Communications

JF - Chemical Communications

IS - 70

ER -

Heterocyclic arsinocarbynes <i>via</i> tandem transmetallation

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