Abstract
Gold(i)-catalysed tandem transmetallation (Sn→Au→As) of the stannylcarbyne [W(≡CSnnBu3)(CO)2(Tp*)] (Tp* = hydrotris-(dimethylpyrazolyl)borate) with haloarsines gives direct access to a range of novel arsinocarbyne complexes, LnM≡CAsR2, including unusual heterocyclic phenarsazininyl and arsolyl examples.
Original language | English |
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Pages (from-to) | 8770-8773 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 57 |
Issue number | 70 |
DOIs | |
Publication status | Published - 11 Sept 2021 |