Heteroleptic Tripalladium(II) Cages

James A. Findlay; Komal M. Patil; Michael G. Gardiner; Hugo I. MacDermott-Opeskin; Megan L. O'Mara; Paul E. Kruger; Dan Preston

doi:10.1002/asia.202200093

Heteroleptic Tripalladium(II) Cages

James A. Findlay, Komal M. Patil, Michael G. Gardiner, Hugo I. MacDermott-Opeskin, Megan L. O'Mara, Paul E. Kruger, Dan Preston^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

There is a concerted attempt to develop self-assembled metallo-cages of greater structural complexity, and heteroleptic Pd^II cages are emerging as prime candidates in these efforts. Most of these are dinuclear: few examples of higher nuclearity have been reported. We demonstrate here a robust method for the formation of tripalladium(II) cages from the 2 : 3 : 3 combination of a tritopic ligand, Pd^II, and a selection of ditopic ligands of the correct size and geometry.

Original language	English
Article number	e202200093
Journal	Chemistry - An Asian Journal
Volume	17
Issue number	6
DOIs	https://doi.org/10.1002/asia.202200093
Publication status	Published - 14 Mar 2022

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title = "Heteroleptic Tripalladium(II) Cages",

abstract = "There is a concerted attempt to develop self-assembled metallo-cages of greater structural complexity, and heteroleptic PdII cages are emerging as prime candidates in these efforts. Most of these are dinuclear: few examples of higher nuclearity have been reported. We demonstrate here a robust method for the formation of tripalladium(II) cages from the 2 : 3 : 3 combination of a tritopic ligand, PdII, and a selection of ditopic ligands of the correct size and geometry.",

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AU - Findlay, James A.

AU - Patil, Komal M.

AU - Gardiner, Michael G.

AU - MacDermott-Opeskin, Hugo I.

AU - O'Mara, Megan L.

AU - Kruger, Paul E.

AU - Preston, Dan

PY - 2022/3/14

Y1 - 2022/3/14

N2 - There is a concerted attempt to develop self-assembled metallo-cages of greater structural complexity, and heteroleptic PdII cages are emerging as prime candidates in these efforts. Most of these are dinuclear: few examples of higher nuclearity have been reported. We demonstrate here a robust method for the formation of tripalladium(II) cages from the 2 : 3 : 3 combination of a tritopic ligand, PdII, and a selection of ditopic ligands of the correct size and geometry.

AB - There is a concerted attempt to develop self-assembled metallo-cages of greater structural complexity, and heteroleptic PdII cages are emerging as prime candidates in these efforts. Most of these are dinuclear: few examples of higher nuclearity have been reported. We demonstrate here a robust method for the formation of tripalladium(II) cages from the 2 : 3 : 3 combination of a tritopic ligand, PdII, and a selection of ditopic ligands of the correct size and geometry.

KW - cages

KW - heteroleptic

KW - metallosupramolecular

KW - palladium(II)

KW - self-assembly

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U2 - 10.1002/asia.202200093

DO - 10.1002/asia.202200093

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VL - 17

JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

IS - 6

M1 - e202200093

ER -

Heteroleptic Tripalladium(II) Cages

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