Heteroleptic Tripalladium(II) Cages

James A. Findlay, Komal M. Patil, Michael G. Gardiner, Hugo I. MacDermott-Opeskin, Megan L. O'Mara, Paul E. Kruger, Dan Preston*

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    19 Citations (Scopus)

    Abstract

    There is a concerted attempt to develop self-assembled metallo-cages of greater structural complexity, and heteroleptic PdII cages are emerging as prime candidates in these efforts. Most of these are dinuclear: few examples of higher nuclearity have been reported. We demonstrate here a robust method for the formation of tripalladium(II) cages from the 2 : 3 : 3 combination of a tritopic ligand, PdII, and a selection of ditopic ligands of the correct size and geometry.

    Original languageEnglish
    Article numbere202200093
    JournalChemistry - An Asian Journal
    Volume17
    Issue number6
    DOIs
    Publication statusPublished - 14 Mar 2022

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