Hexahydroxytriphenylene for the synthesis of group 13 MOFs-a new inorganic building unit in a β-cristobalite type structure

S. Leubner; V. E.G. Bengtsson; A. K. Inge; M. Wahiduzzaman; F. Steinke; A. Jaworski; H. Xu; S. Halis; P. Rönfeldt; H. Reinsch; G. Maurin; X. Zou; N. Stock

doi:10.1039/d0dt00235f

Hexahydroxytriphenylene for the synthesis of group 13 MOFs-a new inorganic building unit in a β-cristobalite type structure

S. Leubner, V. E.G. Bengtsson, A. K. Inge, M. Wahiduzzaman, F. Steinke, A. Jaworski, H. Xu, S. Halis, P. Rönfeldt, H. Reinsch, G. Maurin^*, X. Zou, N. Stock

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Two new, microporous MOFs of framework composition ((CH₃)₂NH₂)₂[M₃O(HHTP)(HHTP)], M = Al³⁺, Ga³⁺, H₆HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene, are described. Electron diffraction combined with molecular simulations show that these compounds crystallize in the β-cristobalite structure, containing a new type of trinuclear inorganic building unit for MOFs and radical anions.

Original language	English
Pages (from-to)	3088-3092
Number of pages	5
Journal	Dalton Transactions
Volume	49
Issue number	10
Early online date	7 Feb 2020
DOIs	https://doi.org/10.1039/d0dt00235f
Publication status	Published - 14 Mar 2020
Externally published	Yes

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Leubner, S., Bengtsson, V. E. G., Inge, A. K., Wahiduzzaman, M., Steinke, F., Jaworski, A., Xu, H., Halis, S., Rönfeldt, P., Reinsch, H., Maurin, G., Zou, X., & Stock, N. (2020). Hexahydroxytriphenylene for the synthesis of group 13 MOFs-a new inorganic building unit in a β-cristobalite type structure. Dalton Transactions, 49(10), 3088-3092. https://doi.org/10.1039/d0dt00235f

@article{6d113eb33c414d49ac861a0cfd9b6058,

title = "Hexahydroxytriphenylene for the synthesis of group 13 MOFs-a new inorganic building unit in a β-cristobalite type structure",

abstract = "Two new, microporous MOFs of framework composition ((CH3)2NH2)2[M3O(HHTP)(HHTP)], M = Al3+, Ga3+, H6HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene, are described. Electron diffraction combined with molecular simulations show that these compounds crystallize in the β-cristobalite structure, containing a new type of trinuclear inorganic building unit for MOFs and radical anions.",

author = "S. Leubner and Bengtsson, {V. E.G.} and Inge, {A. K.} and M. Wahiduzzaman and F. Steinke and A. Jaworski and H. Xu and S. Halis and P. R{\"o}nfeldt and H. Reinsch and G. Maurin and X. Zou and N. Stock",

note = "Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry.",

year = "2020",

month = mar,

day = "14",

doi = "10.1039/d0dt00235f",

language = "English",

volume = "49",

pages = "3088--3092",

journal = "Dalton Transactions",

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Leubner, S, Bengtsson, VEG, Inge, AK, Wahiduzzaman, M, Steinke, F, Jaworski, A, Xu, H, Halis, S, Rönfeldt, P, Reinsch, H, Maurin, G, Zou, X & Stock, N 2020, 'Hexahydroxytriphenylene for the synthesis of group 13 MOFs-a new inorganic building unit in a β-cristobalite type structure', Dalton Transactions, vol. 49, no. 10, pp. 3088-3092. https://doi.org/10.1039/d0dt00235f

TY - JOUR

T1 - Hexahydroxytriphenylene for the synthesis of group 13 MOFs-a new inorganic building unit in a β-cristobalite type structure

AU - Leubner, S.

AU - Bengtsson, V. E.G.

AU - Inge, A. K.

AU - Wahiduzzaman, M.

AU - Steinke, F.

AU - Jaworski, A.

AU - Xu, H.

AU - Halis, S.

AU - Rönfeldt, P.

AU - Reinsch, H.

AU - Maurin, G.

AU - Zou, X.

AU - Stock, N.

PY - 2020/3/14

Y1 - 2020/3/14

N2 - Two new, microporous MOFs of framework composition ((CH3)2NH2)2[M3O(HHTP)(HHTP)], M = Al3+, Ga3+, H6HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene, are described. Electron diffraction combined with molecular simulations show that these compounds crystallize in the β-cristobalite structure, containing a new type of trinuclear inorganic building unit for MOFs and radical anions.

AB - Two new, microporous MOFs of framework composition ((CH3)2NH2)2[M3O(HHTP)(HHTP)], M = Al3+, Ga3+, H6HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene, are described. Electron diffraction combined with molecular simulations show that these compounds crystallize in the β-cristobalite structure, containing a new type of trinuclear inorganic building unit for MOFs and radical anions.

UR - http://www.scopus.com/inward/record.url?scp=85081753031&partnerID=8YFLogxK

U2 - 10.1039/d0dt00235f

DO - 10.1039/d0dt00235f

M3 - Article

C2 - 32051978

AN - SCOPUS:85081753031

SN - 1477-9226

VL - 49

SP - 3088

EP - 3092

JO - Dalton Transactions

JF - Dalton Transactions

IS - 10

ER -

Hexahydroxytriphenylene for the synthesis of group 13 MOFs-a new inorganic building unit in a β-cristobalite type structure

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