Abstract
The (hydrido)(carbido)decaruthenium cluster anion [Ru10(μ-H)(μ6-C)(CO)24]- reacts with triphenylphosphine in a stepwise manner to afford [Ru10(μ-H)(μ6-C)-(CO)24-xPPh3)]- (x = 1–4), with initial ligand displacement on the apical ruthenium associated with the hydride ligand and subsequent ligand substitution at the other apices; the location of the phosphine substituent of the monosubstituted cluster anion [Ru10(μ-H)(μ6-C)-(CO)23PPh3)]- has been confirmed by a single crystal X-ray diffraction study.
Original language | English |
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Pages (from-to) | 1536-1538 |
Number of pages | 3 |
Journal | Organometallics |
Volume | 14 |
Issue number | 3 |
DOIs | |
Publication status | Published - Mar 1995 |