High-Nuclearity Ruthenium Carbonyl Cluster Chemistry. Synthesis and X-ray Structure of [Ru2(μ-H)(μ-NC5H4)2(CO)4(NC5H5)2][Ru10(μ-H)(μ6-C)(CO)24]

Marie P. Cifuentes; Mark G. Humphrey; Brian W. Skelton; Allan H. White

doi:10.1021/om00035a006

High-Nuclearity Ruthenium Carbonyl Cluster Chemistry. Synthesis and X-ray Structure of [Ru₂(μ-H)(μ-NC₅H₄)₂(CO)₄(NC₅H₅)₂][Ru₁₀(μ-H)(μ₆-C)(CO)₂₄]

Marie P. Cifuentes, Mark G. Humphrey^*, Brian W. Skelton, Allan H. White

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Pyrolysis of Ru₃(μ-H)(μ-NC₅H₄)(CO)₁₀ in chlorobenzene results in the formation of [Ru₂(μ-H)(μ- NC₅H₄)₂(CO)₄(NC₅H₅)₂][Ru₁₀(μ-H)(μ₆-C)(CO)₂₄] in high yield; an X-ray structural study suggests that the hydrido ligand in the anion, previously believed to occupy an interstitial tetrahedral site, possibly bridges a metal–metal bond external to the cluster core.

Original language	English
Pages (from-to)	4272-4274
Number of pages	3
Journal	Organometallics
Volume	12
Issue number	11
DOIs	https://doi.org/10.1021/om00035a006
Publication status	Published - 1993
Externally published	Yes

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title = "High-Nuclearity Ruthenium Carbonyl Cluster Chemistry. Synthesis and X-ray Structure of [Ru2(μ-H)(μ-NC5H4)2(CO)4(NC5H5)2][Ru10(μ-H)(μ6-C)(CO)24]",

abstract = "Pyrolysis of Ru3(μ-H)(μ-NC5H4)(CO)10 in chlorobenzene results in the formation of [Ru2(μ-H)(μ- NC5H4)2(CO)4(NC5H5)2][Ru10(μ-H)(μ6-C)(CO)24] in high yield; an X-ray structural study suggests that the hydrido ligand in the anion, previously believed to occupy an interstitial tetrahedral site, possibly bridges a metal–metal bond external to the cluster core.",

author = "Cifuentes, \{Marie P.\} and Humphrey, \{Mark G.\} and Skelton, \{Brian W.\} and White, \{Allan H.\}",

year = "1993",

doi = "10.1021/om00035a006",

language = "English",

volume = "12",

pages = "4272--4274",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "11",

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TY - JOUR

T1 - High-Nuclearity Ruthenium Carbonyl Cluster Chemistry. Synthesis and X-ray Structure of [Ru2(μ-H)(μ-NC5H4)2(CO)4(NC5H5)2][Ru10(μ-H)(μ6-C)(CO)24]

AU - Cifuentes, Marie P.

AU - Humphrey, Mark G.

AU - Skelton, Brian W.

AU - White, Allan H.

PY - 1993

Y1 - 1993

N2 - Pyrolysis of Ru3(μ-H)(μ-NC5H4)(CO)10 in chlorobenzene results in the formation of [Ru2(μ-H)(μ- NC5H4)2(CO)4(NC5H5)2][Ru10(μ-H)(μ6-C)(CO)24] in high yield; an X-ray structural study suggests that the hydrido ligand in the anion, previously believed to occupy an interstitial tetrahedral site, possibly bridges a metal–metal bond external to the cluster core.

AB - Pyrolysis of Ru3(μ-H)(μ-NC5H4)(CO)10 in chlorobenzene results in the formation of [Ru2(μ-H)(μ- NC5H4)2(CO)4(NC5H5)2][Ru10(μ-H)(μ6-C)(CO)24] in high yield; an X-ray structural study suggests that the hydrido ligand in the anion, previously believed to occupy an interstitial tetrahedral site, possibly bridges a metal–metal bond external to the cluster core.

UR - https://www.scopus.com/pages/publications/0000501314

U2 - 10.1021/om00035a006

DO - 10.1021/om00035a006

M3 - Article

AN - SCOPUS:0000501314

SN - 0276-7333

VL - 12

SP - 4272

EP - 4274

JO - Organometallics

JF - Organometallics

IS - 11

ER -

High-Nuclearity Ruthenium Carbonyl Cluster Chemistry. Synthesis and X-ray Structure of [Ru₂(μ-H)(μ-NC₅H₄)₂(CO)₄(NC₅H₅)₂][Ru₁₀(μ-H)(μ₆-C)(CO)₂₄]

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