High oxidation state bromocarbyne complexes

Anthony F. Hill; Richard Y. Kong

doi:10.1039/C6CC08946A

High oxidation state bromocarbyne complexes

Anthony F. Hill^*, Richard Y. Kong

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Bromination of the carbyne complexes [W(≡CR)Br(CO)₂(dcpe)] (R = Ph, SiPh₃; dcpe = 1,2-bis(dicyclohexylphosphino)ethane) provides high oxidation state derivatives [W(≡CPh)Br₃(dcpe)] and [W(≡CBr)Br₃(dcpe)], the latter via an unprecedented bromodesilylation process.

Original language	English
Pages (from-to)	759-762
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	4
DOIs	https://doi.org/10.1039/C6CC08946A
Publication status	Published - 2017

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10.1039/C6CC08946A

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title = "High oxidation state bromocarbyne complexes",

abstract = "Bromination of the carbyne complexes [W(≡CR)Br(CO)2(dcpe)] (R = Ph, SiPh3; dcpe = 1,2-bis(dicyclohexylphosphino)ethane) provides high oxidation state derivatives [W(≡CPh)Br3(dcpe)] and [W(≡CBr)Br3(dcpe)], the latter via an unprecedented bromodesilylation process.",

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AU - Hill, Anthony F.

AU - Kong, Richard Y.

N1 - Publisher Copyright: © The Royal Society of Chemistry.

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Y1 - 2017

N2 - Bromination of the carbyne complexes [W(≡CR)Br(CO)2(dcpe)] (R = Ph, SiPh3; dcpe = 1,2-bis(dicyclohexylphosphino)ethane) provides high oxidation state derivatives [W(≡CPh)Br3(dcpe)] and [W(≡CBr)Br3(dcpe)], the latter via an unprecedented bromodesilylation process.

AB - Bromination of the carbyne complexes [W(≡CR)Br(CO)2(dcpe)] (R = Ph, SiPh3; dcpe = 1,2-bis(dicyclohexylphosphino)ethane) provides high oxidation state derivatives [W(≡CPh)Br3(dcpe)] and [W(≡CBr)Br3(dcpe)], the latter via an unprecedented bromodesilylation process.

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U2 - 10.1039/C6CC08946A

DO - 10.1039/C6CC08946A

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SN - 1359-7345

VL - 53

SP - 759

EP - 762

JO - Chemical Communications

JF - Chemical Communications

IS - 4

ER -

High oxidation state bromocarbyne complexes

Abstract

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