High water diffusivity in low hydration plasma-polymerised proton exchange membranes

Vanessa K. Peterson, Cormac Corr, Gordon J. Kearley, Roderick Boswell, Zunbeltz Izaola

    Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

    1 Citation (Scopus)

    Abstract

    This paper compares proton diffusion through plasma-polymerised proton-exchange membranes (PEMs) produced using traditional wet-chemical methods (NafionR) and those produced using plasma-polymerisation. Using quasielastic neutron scattering and a simple model of proton motion we find the measured diffusion-rate of protons in the plasma-polymerised material and NafionR is the same (within 1 standard error) even though the plasma-polymerised membrane has 80 % less water than the NafionR. We attribute this result to the highly cross-linked structure of the plasma-polymerised membrane.

    Original languageEnglish
    Title of host publicationPRICM7
    PublisherTrans Tech Publications Ltd.
    Pages2871-2874
    Number of pages4
    ISBN (Print)0878492550, 9780878492558
    DOIs
    Publication statusPublished - 2010
    Event7th Pacific Rim International Conference on Advanced Materials and Processing, PRICM-7 - Cairns, QLD, Australia
    Duration: 2 Aug 20106 Aug 2010

    Publication series

    NameMaterials Science Forum
    Volume654-656
    ISSN (Print)0255-5476
    ISSN (Electronic)1662-9752

    Conference

    Conference7th Pacific Rim International Conference on Advanced Materials and Processing, PRICM-7
    Country/TerritoryAustralia
    CityCairns, QLD
    Period2/08/106/08/10

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