Hydride exchange via two-dimensional vibrational tunneling

J. D. Close

doi:10.1063/1.472100

Hydride exchange via two-dimensional vibrational tunneling

J. D. Close^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

We obtain analytic expressions for the zero temperature and finite temperature exchange interaction between two hard sphere fermions bound in a symmetric double-well potential in 1, 2, and 3 dimensions and discuss the effect of dimensionality on the model. The three-dimensional model (due to Zilm/Landesmann) and the two-dimensional model presented here are of relevance to the strongly temperature dependent exchange interaction that has been observed between hydrides bound in metal polyhydride complexes.

Original language	English
Pages (from-to)	2317-2319
Number of pages	3
Journal	Journal of Chemical Physics
Volume	105
Issue number	6
DOIs	https://doi.org/10.1063/1.472100
Publication status	Published - 8 Aug 1996
Externally published	Yes

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10.1063/1.472100

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title = "Hydride exchange via two-dimensional vibrational tunneling",

abstract = "We obtain analytic expressions for the zero temperature and finite temperature exchange interaction between two hard sphere fermions bound in a symmetric double-well potential in 1, 2, and 3 dimensions and discuss the effect of dimensionality on the model. The three-dimensional model (due to Zilm/Landesmann) and the two-dimensional model presented here are of relevance to the strongly temperature dependent exchange interaction that has been observed between hydrides bound in metal polyhydride complexes.",

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AB - We obtain analytic expressions for the zero temperature and finite temperature exchange interaction between two hard sphere fermions bound in a symmetric double-well potential in 1, 2, and 3 dimensions and discuss the effect of dimensionality on the model. The three-dimensional model (due to Zilm/Landesmann) and the two-dimensional model presented here are of relevance to the strongly temperature dependent exchange interaction that has been observed between hydrides bound in metal polyhydride complexes.

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U2 - 10.1063/1.472100

DO - 10.1063/1.472100

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SP - 2317

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JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 6

ER -

Hydride exchange via two-dimensional vibrational tunneling

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