TY - JOUR
T1 - Hydrido(benzochalcogenadiazole) Complexes of Ruthenium - Crystal-structure of [rucl(h)(co)(pph3)2(sn2c6h4)]
AU - Alcock, Nathaniel W.
AU - Hill, Anthony F.
AU - Roe, Mark S.
PY - 1990/5
Y1 - 1990/5
N2 - The complex [RuCl(H)(CO)(PPh3)3] reacts with 2,1,3-benzothiadiazole (C6H4N2S) or 2,1,3-benzoselenadiazole (C6H4N2Se) to provide the compounds [RuCl(H)(CO)(PPh3)2(EN2C6H4)](E = S or Se). An X-ray diffraction study of trans-[RuCl(H)(CO)(PPh3)2(SN2C6H4)] established the mode of heterocycle co-ordination as being through one nitrogen atom and cis to the hydrido ligand. The crystal structure also shows an unusual four-centre interaction between the unco-ordinated N–S multiple bonds of the two molecules of the asymmetric unit.
AB - The complex [RuCl(H)(CO)(PPh3)3] reacts with 2,1,3-benzothiadiazole (C6H4N2S) or 2,1,3-benzoselenadiazole (C6H4N2Se) to provide the compounds [RuCl(H)(CO)(PPh3)2(EN2C6H4)](E = S or Se). An X-ray diffraction study of trans-[RuCl(H)(CO)(PPh3)2(SN2C6H4)] established the mode of heterocycle co-ordination as being through one nitrogen atom and cis to the hydrido ligand. The crystal structure also shows an unusual four-centre interaction between the unco-ordinated N–S multiple bonds of the two molecules of the asymmetric unit.
UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:A1990DD96100034&DestLinkType=FullRecord&DestApp=WOS_CPL
U2 - 10.1039/dt9900001737
DO - 10.1039/dt9900001737
M3 - Comment/debate
SN - 0300-9246
SP - 1737
EP - 1740
JO - Journal of the Chemical Society-dalton Transactions
JF - Journal of the Chemical Society-dalton Transactions
IS - 5
ER -