Hydrogen in amorphous Si and Ge during solid phase epitaxy

Studies into the effect of hydrogen on the kinetics of solid phase epitaxy (SPE) in amorphous Si (a-Si) and Ge (a-Ge) are presented. During SPE, H diffuses into surface amorphous layers from the surface and segregates at the crystalline-amorphous interface. Some of the H crosses the interface and diffuses into the crystalline material where it either leaves the sample or is trapped by defects. H segregation at concentrations up to 2.3 × 10²⁰ H/cm³ is observed in buried pha-Si layers with the SPE rate decreasing by up to 20%. H also results in a reduction of dopant-enhanced SPE rates and is used to explain the asymmetry effects between the SPE velocity profile and the dopant concentration profile observed with shallow dopant implants. Conversely, H diffusion is enhanced by dopants in a-Si. These studies suggest that H diffusion and SPE may be mediated by the same defect. The extent of H in-diffusion into a-Ge surface layers during SPE is about one order of magnitude less that that observed for a-Si layers. This is thought to be due to the lack of a stable surface oxide on a-Ge. However, a considerably greater retarding effect on the SPE rate in a-Ge of up to 70% is observed. A single unifying model is applied to both dopant-enhanced SPE and H diffusion processes.