TY - JOUR
T1 - Hydroruthenation of prop-2-ynyltriphenylphosphonium bromide
T2 - Synthesis, crystal structure and reactions of [RuBr(CH=CHCH2PPh 3)(CO)(PPh3)2]PF6
AU - Alcock, Nathaniel W.
AU - Cartwright, Jonathan
AU - Hill, Anthony F.
AU - Marcellin, Monique
AU - Rawles, Heath M.
PY - 1995
Y1 - 1995
N2 - The reaction of the complex [RuClH(CO)(PPh3)3] with prop-2-ynyltriphenylphosphonium bromide ([Ph3PCH2C≡ CH]Br) followed by NH4PF6 provides the crystallographically characterised salt [RuBr(CH=CHCH2PPh 3)(CO)(PPh3)2]PF6 which by virtue of the coordinative unsaturation at the ruthenium centre undergoes addition of the ligands CNC6H3Me2-2,6, and CO to Ru and insertion of SO2 into the Ru-C σ-bond.
AB - The reaction of the complex [RuClH(CO)(PPh3)3] with prop-2-ynyltriphenylphosphonium bromide ([Ph3PCH2C≡ CH]Br) followed by NH4PF6 provides the crystallographically characterised salt [RuBr(CH=CHCH2PPh 3)(CO)(PPh3)2]PF6 which by virtue of the coordinative unsaturation at the ruthenium centre undergoes addition of the ligands CNC6H3Me2-2,6, and CO to Ru and insertion of SO2 into the Ru-C σ-bond.
KW - Ruthenatetraboranes
UR - http://www.scopus.com/inward/record.url?scp=37049072731&partnerID=8YFLogxK
U2 - 10.1039/C39950000369
DO - 10.1039/C39950000369
M3 - Article
AN - SCOPUS:37049072731
SN - 0022-4936
SP - 369
EP - 370
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 3
ER -