Hydrosulfination of alkynes: Synthesis of vinyl sulfinato complexes of ruthenium(II)

Anthony F. Hill

doi:10.1039/C39950000741

Hydrosulfination of alkynes: Synthesis of vinyl sulfinato complexes of ruthenium(II)

Anthony F. Hill^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The reaction of [RuClH(CO)(PPh₃)₃] with alkynes (R¹C≡CR²) and SO₂ provides the vinylsulfinate-S,O complexes [Ru(η²-SO₂CR ¹=CHR²)Cl(CO)(PPh₃)₂] in a process reminiscent of hydroformylation.

Original language	English
Pages (from-to)	741
Number of pages	1
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	7
DOIs	https://doi.org/10.1039/C39950000741
Publication status	Published - 1995
Externally published	Yes

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title = "Hydrosulfination of alkynes: Synthesis of vinyl sulfinato complexes of ruthenium(II)",

abstract = "The reaction of [RuClH(CO)(PPh3)3] with alkynes (R1C≡CR2) and SO2 provides the vinylsulfinate-S,O complexes [Ru(η2-SO2CR 1=CHR2)Cl(CO)(PPh3)2] in a process reminiscent of hydroformylation.",

author = "Hill, {Anthony F.}",

year = "1995",

doi = "10.1039/C39950000741",

language = "English",

pages = "741",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "7",

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TY - JOUR

T1 - Hydrosulfination of alkynes

T2 - Synthesis of vinyl sulfinato complexes of ruthenium(II)

AU - Hill, Anthony F.

PY - 1995

Y1 - 1995

N2 - The reaction of [RuClH(CO)(PPh3)3] with alkynes (R1C≡CR2) and SO2 provides the vinylsulfinate-S,O complexes [Ru(η2-SO2CR 1=CHR2)Cl(CO)(PPh3)2] in a process reminiscent of hydroformylation.

AB - The reaction of [RuClH(CO)(PPh3)3] with alkynes (R1C≡CR2) and SO2 provides the vinylsulfinate-S,O complexes [Ru(η2-SO2CR 1=CHR2)Cl(CO)(PPh3)2] in a process reminiscent of hydroformylation.

UR - http://www.scopus.com/inward/record.url?scp=37049083136&partnerID=8YFLogxK

U2 - 10.1039/C39950000741

DO - 10.1039/C39950000741

M3 - Article

AN - SCOPUS:37049083136

SN - 0022-4936

SP - 741

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 7

ER -

Hydrosulfination of alkynes: Synthesis of vinyl sulfinato complexes of ruthenium(II)

Abstract

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