Hysteretic spin crossover in iron(ii) complexes of a new pyridine–triazole–pyrazine ligand is tuned by choice of NCE co-ligand

Ross W. Hogue, Reece G. Miller, Nicholas G. White, Humphrey L.C. Feltham, Guy N.L. Jameson, Sally Brooker*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

34 Citations (Scopus)

Abstract

A family of three new mononuclear complexes of the general form [Fe(Lpz)2(NCE)2] has been prepared (Lpz = 4-p-tolyl-3-(2-pyrazinyl)-5-(2-pyridyl)-1,2,4-triazole; E = S, Se, BH3). All three exhibit spin crossover, in two cases with hysteresis, with T1/2 being predictably tuned by varying the coordinated anion.

Original languageEnglish
Pages (from-to)1435-1437
Number of pages3
JournalChemical Communications
Volume50
Issue number12
DOIs
Publication statusPublished - 14 Jan 2014
Externally publishedYes

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