Identification of the 3pπue′ 3Δu Rydberg state of O2 by (3+1) resonance-enhanced multiphoton-ionization spectroscopy

B. R. Lewis; S. T. Gibson; Aurea A. Tucay; Robert Robertson; Eunsook S. Hwang; Aaron Bergman; Richard A. Copeland

doi:10.1063/1.1367333

Identification of the 3pπ_ue′ ³Δ_u Rydberg state of O₂ by (3+1) resonance-enhanced multiphoton-ionization spectroscopy

B. R. Lewis^*, S. T. Gibson, Aurea A. Tucay, Robert Robertson, Eunsook S. Hwang, Aaron Bergman, Richard A. Copeland

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The diffusive v=0 levels of the 3pπ_ue′ Δ_u Rydberg state of O₂ were identified and characterized using (31) resonance-enhanced multiphoton-ionization spectroscopy. As a result, the e′(v=0,1, and 4) levels, e′ ³Δ_1u(F₁) and e′ ³Δ_3u(F₃) sublevels were observed for the first time. An experimental potential-energy curve for the e′ state, together with the magnitude of its interaction with the A′ ³Δ_u valence state were determined semiempirically.

Original language	English
Pages (from-to)	8364-8371
Number of pages	8
Journal	Journal of Chemical Physics
Volume	114
Issue number	19
DOIs	https://doi.org/10.1063/1.1367333
Publication status	Published - 15 May 2001

Access to Document

10.1063/1.1367333

Cite this

@article{eec2d20b8f8e4b138dbb22d0097b8354,

title = "Identification of the 3pπue′ 3Δu Rydberg state of O2 by (3+1) resonance-enhanced multiphoton-ionization spectroscopy",

abstract = "The diffusive v=0 levels of the 3pπue′ Δu Rydberg state of O2 were identified and characterized using (31) resonance-enhanced multiphoton-ionization spectroscopy. As a result, the e′(v=0,1, and 4) levels, e′ 3Δ1u(F1) and e′ 3Δ3u(F3) sublevels were observed for the first time. An experimental potential-energy curve for the e′ state, together with the magnitude of its interaction with the A′ 3Δu valence state were determined semiempirically.",

author = "Lewis, {B. R.} and Gibson, {S. T.} and Tucay, {Aurea A.} and Robert Robertson and Hwang, {Eunsook S.} and Aaron Bergman and Copeland, {Richard A.}",

year = "2001",

month = may,

day = "15",

doi = "10.1063/1.1367333",

language = "English",

volume = "114",

pages = "8364--8371",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "19",

}

TY - JOUR

T1 - Identification of the 3pπue′ 3Δu Rydberg state of O2 by (3+1) resonance-enhanced multiphoton-ionization spectroscopy

AU - Lewis, B. R.

AU - Gibson, S. T.

AU - Tucay, Aurea A.

AU - Robertson, Robert

AU - Hwang, Eunsook S.

AU - Bergman, Aaron

AU - Copeland, Richard A.

PY - 2001/5/15

Y1 - 2001/5/15

N2 - The diffusive v=0 levels of the 3pπue′ Δu Rydberg state of O2 were identified and characterized using (31) resonance-enhanced multiphoton-ionization spectroscopy. As a result, the e′(v=0,1, and 4) levels, e′ 3Δ1u(F1) and e′ 3Δ3u(F3) sublevels were observed for the first time. An experimental potential-energy curve for the e′ state, together with the magnitude of its interaction with the A′ 3Δu valence state were determined semiempirically.

AB - The diffusive v=0 levels of the 3pπue′ Δu Rydberg state of O2 were identified and characterized using (31) resonance-enhanced multiphoton-ionization spectroscopy. As a result, the e′(v=0,1, and 4) levels, e′ 3Δ1u(F1) and e′ 3Δ3u(F3) sublevels were observed for the first time. An experimental potential-energy curve for the e′ state, together with the magnitude of its interaction with the A′ 3Δu valence state were determined semiempirically.

UR - http://www.scopus.com/inward/record.url?scp=0035872754&partnerID=8YFLogxK

U2 - 10.1063/1.1367333

DO - 10.1063/1.1367333

M3 - Article

SN - 0021-9606

VL - 114

SP - 8364

EP - 8371

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 19

ER -

Identification of the 3pπ_ue′ ³Δ_u Rydberg state of O₂ by (3+1) resonance-enhanced multiphoton-ionization spectroscopy

Abstract

Access to Document

Other files and links

Fingerprint

Cite this