In situ formed [M(CN)9] (M = W, Mo) as a building block for the construction of two nona-cyanometalate-bridged heterometallic coordination polymers

Jun Qian; Hirofumi Yoshikawa; Mark G. Humphrey; Jinfang Zhang; Kunio Awaga; Chi Zhang

doi:10.1039/c9ce00579j

In situ formed [M(CN)₉] (M = W, Mo) as a building block for the construction of two nona-cyanometalate-bridged heterometallic coordination polymers

Jun Qian, Hirofumi Yoshikawa, Mark G. Humphrey, Jinfang Zhang, Kunio Awaga, Chi Zhang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Two interesting nona-cyanometalate-based coordination polymers (CPs) {[μ₄-M(CN)₉Mn₂(dpo)₂(DMF)₄]·DMF}_n (M = W 1, Mo 2) were obtained from the reaction of 2,5-di(4-pyridyl)-1,3,4-oxadiazole (dpo) and (Bu₃NH)₃[M(CN)₈] (M = W, Mo) with Mn(NO₃)₂·6H₂O in DMF. It is noteworthy that the in situ generated [M(CN)₉]^4- (M = W, Mo), the first nona-cyanometalate-based example of precursor, plays the roles of not only the charge-balancing counter anion but also the molecular building blocks in inducing the neutral structures of CPs 1 and 2. Single-crystal diffraction analysis reveals that CPs 1 and 2 crystallize in the tetragonal crystal system with the I4/m space group and possess the same 3D framework structure in a (4,4)-connected mot topology with the point symbol {6⁶}{6⁴·8²}₂. Variable-temperature magnetic susceptibility measurements in the temperature range of 2 to 300 K reveal that there are antiferromagnetic interactions between the M^V (M = W, Mo) of nona-cyanometalate [M(CN)₉]^4- and Mn^II spin centers in both CPs 1 and 2.

Original language	English
Pages (from-to)	4363-4372
Number of pages	10
Journal	CrystEngComm
Volume	21
Issue number	29
DOIs	https://doi.org/10.1039/c9ce00579j
Publication status	Published - 2019

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title = "In situ formed [M(CN)9] (M = W, Mo) as a building block for the construction of two nona-cyanometalate-bridged heterometallic coordination polymers",

abstract = "Two interesting nona-cyanometalate-based coordination polymers (CPs) {[μ4-M(CN)9Mn2(dpo)2(DMF)4]·DMF}n (M = W 1, Mo 2) were obtained from the reaction of 2,5-di(4-pyridyl)-1,3,4-oxadiazole (dpo) and (Bu3NH)3[M(CN)8] (M = W, Mo) with Mn(NO3)2·6H2O in DMF. It is noteworthy that the in situ generated [M(CN)9]4- (M = W, Mo), the first nona-cyanometalate-based example of precursor, plays the roles of not only the charge-balancing counter anion but also the molecular building blocks in inducing the neutral structures of CPs 1 and 2. Single-crystal diffraction analysis reveals that CPs 1 and 2 crystallize in the tetragonal crystal system with the I4/m space group and possess the same 3D framework structure in a (4,4)-connected mot topology with the point symbol {66}{64·82}2. Variable-temperature magnetic susceptibility measurements in the temperature range of 2 to 300 K reveal that there are antiferromagnetic interactions between the MV (M = W, Mo) of nona-cyanometalate [M(CN)9]4- and MnII spin centers in both CPs 1 and 2.",

author = "Jun Qian and Hirofumi Yoshikawa and Humphrey, {Mark G.} and Jinfang Zhang and Kunio Awaga and Chi Zhang",

note = "Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9ce00579j",

language = "English",

volume = "21",

pages = "4363--4372",

journal = "CrystEngComm",

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publisher = "Royal Society of Chemistry",

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T1 - In situ formed [M(CN)9] (M = W, Mo) as a building block for the construction of two nona-cyanometalate-bridged heterometallic coordination polymers

AU - Qian, Jun

AU - Yoshikawa, Hirofumi

AU - Humphrey, Mark G.

AU - Zhang, Jinfang

AU - Awaga, Kunio

AU - Zhang, Chi

PY - 2019

Y1 - 2019

N2 - Two interesting nona-cyanometalate-based coordination polymers (CPs) {[μ4-M(CN)9Mn2(dpo)2(DMF)4]·DMF}n (M = W 1, Mo 2) were obtained from the reaction of 2,5-di(4-pyridyl)-1,3,4-oxadiazole (dpo) and (Bu3NH)3[M(CN)8] (M = W, Mo) with Mn(NO3)2·6H2O in DMF. It is noteworthy that the in situ generated [M(CN)9]4- (M = W, Mo), the first nona-cyanometalate-based example of precursor, plays the roles of not only the charge-balancing counter anion but also the molecular building blocks in inducing the neutral structures of CPs 1 and 2. Single-crystal diffraction analysis reveals that CPs 1 and 2 crystallize in the tetragonal crystal system with the I4/m space group and possess the same 3D framework structure in a (4,4)-connected mot topology with the point symbol {66}{64·82}2. Variable-temperature magnetic susceptibility measurements in the temperature range of 2 to 300 K reveal that there are antiferromagnetic interactions between the MV (M = W, Mo) of nona-cyanometalate [M(CN)9]4- and MnII spin centers in both CPs 1 and 2.

AB - Two interesting nona-cyanometalate-based coordination polymers (CPs) {[μ4-M(CN)9Mn2(dpo)2(DMF)4]·DMF}n (M = W 1, Mo 2) were obtained from the reaction of 2,5-di(4-pyridyl)-1,3,4-oxadiazole (dpo) and (Bu3NH)3[M(CN)8] (M = W, Mo) with Mn(NO3)2·6H2O in DMF. It is noteworthy that the in situ generated [M(CN)9]4- (M = W, Mo), the first nona-cyanometalate-based example of precursor, plays the roles of not only the charge-balancing counter anion but also the molecular building blocks in inducing the neutral structures of CPs 1 and 2. Single-crystal diffraction analysis reveals that CPs 1 and 2 crystallize in the tetragonal crystal system with the I4/m space group and possess the same 3D framework structure in a (4,4)-connected mot topology with the point symbol {66}{64·82}2. Variable-temperature magnetic susceptibility measurements in the temperature range of 2 to 300 K reveal that there are antiferromagnetic interactions between the MV (M = W, Mo) of nona-cyanometalate [M(CN)9]4- and MnII spin centers in both CPs 1 and 2.

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DO - 10.1039/c9ce00579j

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IS - 29

ER -

In situ formed [M(CN)₉] (M = W, Mo) as a building block for the construction of two nona-cyanometalate-bridged heterometallic coordination polymers

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