Independent switching of cubic nonlinear optical properties in a ruthenium alkynyl cruciform complex by employing protic and electrochemical stimuli

Gulliver T. Dalton; Marie P. Cifuentes; Simon Petrie; Robert Stranger; Mark G. Humphrey; Marek Samoc

doi:10.1021/ja074205k

Independent switching of cubic nonlinear optical properties in a ruthenium alkynyl cruciform complex by employing protic and electrochemical stimuli

Gulliver T. Dalton, Marie P. Cifuentes, Simon Petrie, Robert Stranger, Mark G. Humphrey^*, Marek Samoc

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

86 Citations (Scopus)

Abstract

The quadrupolar ruthenium alkynyl cruciform complex is reversibly converted to tetravinylidene complex or tetraruthenium(III) tetracationic complex forms by protonation or oxidation, respectively; linear and nonlinear proto- and electrochromism studies reveal independent switching of NLO properties by the protic and electrochemical stimuli, respectively, aspects of which have been rationalized by theoretical studies.

Original language	English
Pages (from-to)	11882-11883
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	39
DOIs	https://doi.org/10.1021/ja074205k
Publication status	Published - 3 Oct 2007

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title = "Independent switching of cubic nonlinear optical properties in a ruthenium alkynyl cruciform complex by employing protic and electrochemical stimuli",

abstract = "The quadrupolar ruthenium alkynyl cruciform complex is reversibly converted to tetravinylidene complex or tetraruthenium(III) tetracationic complex forms by protonation or oxidation, respectively; linear and nonlinear proto- and electrochromism studies reveal independent switching of NLO properties by the protic and electrochemical stimuli, respectively, aspects of which have been rationalized by theoretical studies.",

author = "Dalton, \{Gulliver T.\} and Cifuentes, \{Marie P.\} and Simon Petrie and Robert Stranger and Humphrey, \{Mark G.\} and Marek Samoc",

year = "2007",

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doi = "10.1021/ja074205k",

language = "English",

volume = "129",

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journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

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Independent switching of cubic nonlinear optical properties in a ruthenium alkynyl cruciform complex by employing protic and electrochemical stimuli. / Dalton, Gulliver T.; Cifuentes, Marie P.; Petrie, Simon et al.
In: Journal of the American Chemical Society, Vol. 129, No. 39, 03.10.2007, p. 11882-11883.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Independent switching of cubic nonlinear optical properties in a ruthenium alkynyl cruciform complex by employing protic and electrochemical stimuli

AU - Dalton, Gulliver T.

AU - Cifuentes, Marie P.

AU - Petrie, Simon

AU - Stranger, Robert

AU - Humphrey, Mark G.

AU - Samoc, Marek

PY - 2007/10/3

Y1 - 2007/10/3

N2 - The quadrupolar ruthenium alkynyl cruciform complex is reversibly converted to tetravinylidene complex or tetraruthenium(III) tetracationic complex forms by protonation or oxidation, respectively; linear and nonlinear proto- and electrochromism studies reveal independent switching of NLO properties by the protic and electrochemical stimuli, respectively, aspects of which have been rationalized by theoretical studies.

AB - The quadrupolar ruthenium alkynyl cruciform complex is reversibly converted to tetravinylidene complex or tetraruthenium(III) tetracationic complex forms by protonation or oxidation, respectively; linear and nonlinear proto- and electrochromism studies reveal independent switching of NLO properties by the protic and electrochemical stimuli, respectively, aspects of which have been rationalized by theoretical studies.

UR - https://www.scopus.com/pages/publications/34848830441

U2 - 10.1021/ja074205k

DO - 10.1021/ja074205k

M3 - Article

SN - 0002-7863

VL - 129

SP - 11882

EP - 11883

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 39

ER -

Independent switching of cubic nonlinear optical properties in a ruthenium alkynyl cruciform complex by employing protic and electrochemical stimuli

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