Influence of the selenium content on thermo-mechanical and optical properties of Ge-Ga-Sb-S chalcogenide glasses

Bin Ye; Shixun Dai; Rongping Wang; Guangming Tao; Peiqing Zhang; Xunsi Wang; Xiang Shen

doi:10.1016/j.infrared.2016.05.013

Influence of the selenium content on thermo-mechanical and optical properties of Ge-Ga-Sb-S chalcogenide glasses

Bin Ye
, Shixun Dai^*
, Rongping Wang
, Guangming Tao
, Peiqing Zhang
, Xunsi Wang
, Xiang Shen

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

A number of Ge₁₇Ga₄Sb₁₀S_69-_xSe_x (x = 0, 15, 30, 45, 60, and 69) chalcogenide glasses have been synthesized by a melt-quenching method to investigate the effect of the Se content on thermo-mechanical and optical properties of these glasses. While it was found that the glass transition temperature (T_g) decreases from 261 to 174 °C with increasing Se contents, crystallization temperature (T_c) peak only be observed in glasses with Se content of x = 45. It was evident from the measurements of structural and physical properties that changes of the glass network bring an apparent impact on the glass properties. Also, the substitution of Se for S in Ge-Ga-Sb glasses can significantly improve the thermal stability against crystallization and broaden the infrared transmission region.

Original language	English
Pages (from-to)	21-26
Number of pages	6
Journal	Infrared Physics and Technology
Volume	77
DOIs	https://doi.org/10.1016/j.infrared.2016.05.013
Publication status	Published - 1 Jul 2016

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10.1016/j.infrared.2016.05.013

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title = "Influence of the selenium content on thermo-mechanical and optical properties of Ge-Ga-Sb-S chalcogenide glasses",

abstract = "A number of Ge17Ga4Sb10S69-xSex (x = 0, 15, 30, 45, 60, and 69) chalcogenide glasses have been synthesized by a melt-quenching method to investigate the effect of the Se content on thermo-mechanical and optical properties of these glasses. While it was found that the glass transition temperature (Tg) decreases from 261 to 174 °C with increasing Se contents, crystallization temperature (Tc) peak only be observed in glasses with Se content of x = 45. It was evident from the measurements of structural and physical properties that changes of the glass network bring an apparent impact on the glass properties. Also, the substitution of Se for S in Ge-Ga-Sb glasses can significantly improve the thermal stability against crystallization and broaden the infrared transmission region.",

keywords = "Chalcogenide glasses, Infrared transmission region, Thermo-mechanical and optical properties",

author = "Bin Ye and Shixun Dai and Rongping Wang and Guangming Tao and Peiqing Zhang and Xunsi Wang and Xiang Shen",

note = "Publisher Copyright: {\textcopyright} 2016 Published by Elsevier B.V.",

year = "2016",

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day = "1",

doi = "10.1016/j.infrared.2016.05.013",

language = "English",

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journal = "Infrared Physics and Technology",

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TY - JOUR

T1 - Influence of the selenium content on thermo-mechanical and optical properties of Ge-Ga-Sb-S chalcogenide glasses

AU - Ye, Bin

AU - Dai, Shixun

AU - Wang, Rongping

AU - Tao, Guangming

AU - Zhang, Peiqing

AU - Wang, Xunsi

AU - Shen, Xiang

PY - 2016/7/1

Y1 - 2016/7/1

N2 - A number of Ge17Ga4Sb10S69-xSex (x = 0, 15, 30, 45, 60, and 69) chalcogenide glasses have been synthesized by a melt-quenching method to investigate the effect of the Se content on thermo-mechanical and optical properties of these glasses. While it was found that the glass transition temperature (Tg) decreases from 261 to 174 °C with increasing Se contents, crystallization temperature (Tc) peak only be observed in glasses with Se content of x = 45. It was evident from the measurements of structural and physical properties that changes of the glass network bring an apparent impact on the glass properties. Also, the substitution of Se for S in Ge-Ga-Sb glasses can significantly improve the thermal stability against crystallization and broaden the infrared transmission region.

AB - A number of Ge17Ga4Sb10S69-xSex (x = 0, 15, 30, 45, 60, and 69) chalcogenide glasses have been synthesized by a melt-quenching method to investigate the effect of the Se content on thermo-mechanical and optical properties of these glasses. While it was found that the glass transition temperature (Tg) decreases from 261 to 174 °C with increasing Se contents, crystallization temperature (Tc) peak only be observed in glasses with Se content of x = 45. It was evident from the measurements of structural and physical properties that changes of the glass network bring an apparent impact on the glass properties. Also, the substitution of Se for S in Ge-Ga-Sb glasses can significantly improve the thermal stability against crystallization and broaden the infrared transmission region.

KW - Chalcogenide glasses

KW - Infrared transmission region

KW - Thermo-mechanical and optical properties

UR - https://www.scopus.com/pages/publications/84969528762

U2 - 10.1016/j.infrared.2016.05.013

DO - 10.1016/j.infrared.2016.05.013

M3 - Article

SN - 1350-4495

VL - 77

SP - 21

EP - 26

JO - Infrared Physics and Technology

JF - Infrared Physics and Technology

ER -

Influence of the selenium content on thermo-mechanical and optical properties of Ge-Ga-Sb-S chalcogenide glasses

Abstract

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