Intramolecular thioacyl hydroboration: Synthesis of [W(eta(2)-S2CR)(CO)(2){eta(3)-HB(pz)(2)(SCH2R)}] (pz equals pyrazol-1-yl, R equals C6H4Me-4)

AF Hill; JM Malget

doi:10.1039/a701040k

Intramolecular thioacyl hydroboration: Synthesis of [W(eta(2)-S2CR)(CO)(2){eta(3)-HB(pz)(2)(SCH2R)}] (pz equals pyrazol-1-yl, R equals C6H4Me-4)

AF Hill, JM Malget

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

The sequential treatment of [W(=CR)Br(CO)(4)] (R = C6H4-Me-4) with sulfur and K[HnB(pz)(4-n)] (n = 1 or 2; pz = pyrazol-1-yl) provided [W(eta(2)-S2CR)(CO)(2){HB(pz)(3)}] or [W(eta(2)-S2CR)-(CO)(2){eta(3)-HB(pz)(2)(SCH2R)}], the latter via an unusual reduction of the alkylidyne-tungsten linkage.

Original language	English
Pages (from-to)	2003-2004
Number of pages	2
Journal	Journal of the Chemical Society-dalton Transactions
Issue number	12
DOIs	https://doi.org/10.1039/a701040k
Publication status	Published - 21 Jun 1997
Externally published	Yes

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@article{d15237ff4ec7459d947fa79dcd9da561,

title = "Intramolecular thioacyl hydroboration: Synthesis of [W(eta(2)-S2CR)(CO)(2){eta(3)-HB(pz)(2)(SCH2R)}] (pz equals pyrazol-1-yl, R equals C6H4Me-4)",

abstract = "The sequential treatment of [W(=CR)Br(CO)(4)] (R = C6H4-Me-4) with sulfur and K[HnB(pz)(4-n)] (n = 1 or 2; pz = pyrazol-1-yl) provided [W(eta(2)-S2CR)(CO)(2){HB(pz)(3)}] or [W(eta(2)-S2CR)-(CO)(2){eta(3)-HB(pz)(2)(SCH2R)}], the latter via an unusual reduction of the alkylidyne-tungsten linkage.",

keywords = "Crystal-structures, Complexes, Alkylidyne, Carbene, Ligands, Metal",

author = "AF Hill and JM Malget",

year = "1997",

month = jun,

day = "21",

doi = "10.1039/a701040k",

language = "English",

pages = "2003--2004",

journal = "Journal of the Chemical Society-dalton Transactions",

issn = "0300-9246",

publisher = "Royal Soc Chemistry",

number = "12",

}

TY - JOUR

T1 - Intramolecular thioacyl hydroboration

T2 - Synthesis of [W(eta(2)-S2CR)(CO)(2){eta(3)-HB(pz)(2)(SCH2R)}] (pz equals pyrazol-1-yl, R equals C6H4Me-4)

AU - Hill, AF

AU - Malget, JM

PY - 1997/6/21

Y1 - 1997/6/21

N2 - The sequential treatment of [W(=CR)Br(CO)(4)] (R = C6H4-Me-4) with sulfur and K[HnB(pz)(4-n)] (n = 1 or 2; pz = pyrazol-1-yl) provided [W(eta(2)-S2CR)(CO)(2){HB(pz)(3)}] or [W(eta(2)-S2CR)-(CO)(2){eta(3)-HB(pz)(2)(SCH2R)}], the latter via an unusual reduction of the alkylidyne-tungsten linkage.

AB - The sequential treatment of [W(=CR)Br(CO)(4)] (R = C6H4-Me-4) with sulfur and K[HnB(pz)(4-n)] (n = 1 or 2; pz = pyrazol-1-yl) provided [W(eta(2)-S2CR)(CO)(2){HB(pz)(3)}] or [W(eta(2)-S2CR)-(CO)(2){eta(3)-HB(pz)(2)(SCH2R)}], the latter via an unusual reduction of the alkylidyne-tungsten linkage.

KW - Crystal-structures

KW - Complexes

KW - Alkylidyne

KW - Carbene

KW - Ligands

KW - Metal

UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:A1997XH76600002&DestLinkType=FullRecord&DestApp=WOS_CPL

U2 - 10.1039/a701040k

DO - 10.1039/a701040k

M3 - Article

SN - 0300-9246

SP - 2003

EP - 2004

JO - Journal of the Chemical Society-dalton Transactions

JF - Journal of the Chemical Society-dalton Transactions

IS - 12

ER -

Intramolecular thioacyl hydroboration: Synthesis of [W(eta(2)-S2CR)(CO)(2){eta(3)-HB(pz)(2)(SCH2R)}] (pz equals pyrazol-1-yl, R equals C6H4Me-4)

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