Iridium tricarbido complexes via transmetallation with tricarbidomercurials

Rian D. Dewhurst; Anthony F. Hill; Anthony C. Willis

doi:10.1039/b900205g

Iridium tricarbido complexes via transmetallation with tricarbidomercurials

Rian D. Dewhurst, Anthony F. Hill, Anthony C. Willis

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The reactions of Vaska's complex with [Hg{CCCW(CO)₂(L)} ₂] (L = HB(pz)₃, HB(pzMe₂)₃, pz = pyrazol-1-yl) unexpectedly provide the structurally characterized tetrametallic trans-bis(tricarbido)complex [Ir(HgCl){CCCW(CO)₂(L)} ₂(CO)(PPh₃)₂].

Original language	English
Pages (from-to)	3384-3387
Number of pages	4
Journal	Dalton Transactions
Issue number	18
DOIs	https://doi.org/10.1039/b900205g
Publication status	Published - 2009

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@article{405c30ac514f4ab5a6049aca4e4a349b,

title = "Iridium tricarbido complexes via transmetallation with tricarbidomercurials",

abstract = "The reactions of Vaska's complex with [Hg{CCCW(CO)2(L)} 2] (L = HB(pz)3, HB(pzMe2)3, pz = pyrazol-1-yl) unexpectedly provide the structurally characterized tetrametallic trans-bis(tricarbido)complex [Ir(HgCl){CCCW(CO)2(L)} 2(CO)(PPh3)2].",

author = "Dewhurst, {Rian D.} and Hill, {Anthony F.} and Willis, {Anthony C.}",

year = "2009",

doi = "10.1039/b900205g",

language = "English",

pages = "3384--3387",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "18",

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T1 - Iridium tricarbido complexes via transmetallation with tricarbidomercurials

AU - Dewhurst, Rian D.

AU - Hill, Anthony F.

AU - Willis, Anthony C.

PY - 2009

Y1 - 2009

N2 - The reactions of Vaska's complex with [Hg{CCCW(CO)2(L)} 2] (L = HB(pz)3, HB(pzMe2)3, pz = pyrazol-1-yl) unexpectedly provide the structurally characterized tetrametallic trans-bis(tricarbido)complex [Ir(HgCl){CCCW(CO)2(L)} 2(CO)(PPh3)2].

AB - The reactions of Vaska's complex with [Hg{CCCW(CO)2(L)} 2] (L = HB(pz)3, HB(pzMe2)3, pz = pyrazol-1-yl) unexpectedly provide the structurally characterized tetrametallic trans-bis(tricarbido)complex [Ir(HgCl){CCCW(CO)2(L)} 2(CO)(PPh3)2].

UR - http://www.scopus.com/inward/record.url?scp=65349122392&partnerID=8YFLogxK

U2 - 10.1039/b900205g

DO - 10.1039/b900205g

M3 - Article

SN - 1477-9226

SP - 3384

EP - 3387

JO - Dalton Transactions

JF - Dalton Transactions

IS - 18

ER -

Iridium tricarbido complexes via transmetallation with tricarbidomercurials

Abstract

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