TY - JOUR
T1 - Kinetic study of the collisional quenching of spin-orbitally excited atomic chlorine, Cl(2P1/2), by H2O, D2O, and H2O2
AU - Kono, Mitsuhiko
AU - Takahashi, Kenshi
AU - Matsumi, Yutaka
PY - 2006/1/25
Y1 - 2006/1/25
N2 - Rate constants for the collisional quenching of spin-orbitally excited Cl(2P1/2) atoms by H2O, D2O, and H2O2 were determined at ∼295 K using laser-flash photolysis and laser-induced fluorescence techniques in the vacuum ultraviolet energy region. The rate constants reported for the quenchers of H2O, D2O, and H2O2, are (3.9 ± 0.3) × 10-11, (4.7 ± 0.3) × 10-11, and (3.1 ± 0.3) × 10-10 cm3 molecules-1 s -1, where the uncertainties correspond to 1σ, respectively.
AB - Rate constants for the collisional quenching of spin-orbitally excited Cl(2P1/2) atoms by H2O, D2O, and H2O2 were determined at ∼295 K using laser-flash photolysis and laser-induced fluorescence techniques in the vacuum ultraviolet energy region. The rate constants reported for the quenchers of H2O, D2O, and H2O2, are (3.9 ± 0.3) × 10-11, (4.7 ± 0.3) × 10-11, and (3.1 ± 0.3) × 10-10 cm3 molecules-1 s -1, where the uncertainties correspond to 1σ, respectively.
UR - http://www.scopus.com/inward/record.url?scp=30344466967&partnerID=8YFLogxK
U2 - 10.1016/j.cplett.2005.10.078
DO - 10.1016/j.cplett.2005.10.078
M3 - Article
SN - 0009-2614
VL - 418
SP - 15
EP - 18
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 1-3
ER -