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Leading-order behavior of the correlation energy in the uniform electron gas

Pierre François Loos, Peter M.W. Gill*

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    7 Citations (Scopus)

    Abstract

    We show that, in the high-density limit, restricted Møller-Plesset (RMP) perturbation theory yields E RMP (2) = π -2(1 - ln 2) ln r s + O(r s 0) for the correlation energy per electron in the uniform electron gas, where r s is the Seitz radius. This contradicts an earlier derivation which yielded E RMP (2) = O(ln|ln r s|). The reason for the discrepancy is explained.

    Original languageEnglish
    Pages (from-to)1712-1716
    Number of pages5
    JournalInternational Journal of Quantum Chemistry
    Volume112
    Issue number6
    DOIs
    Publication statusPublished - 15 Mar 2012

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