Low-Coordinate Cobalt(I) Complexes Stabilized by an Extremely Bulky Amide Ligand

Jamie Hicks; Cameron Jones

doi:10.1021/om501233f

Low-Coordinate Cobalt(I) Complexes Stabilized by an Extremely Bulky Amide Ligand

Jamie Hicks, Cameron Jones^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

A series of low-coordinate, high-spin, mono- and dinuclear cobalt(I) complexes bearing an extremely bulky amide (La″ = N(Ar∗)(SiPh₃); Ar∗ = C₆H₂{C(H)Ph₂}₂Me-2,6,4) ligand have been synthesized and characterized. These include the first example of a neutral two-coordinate cobalt(I) complex, [La″Co(IPriMe)] (IPriMe =:C{N(Prⁱ)C(Me)}₂), which has a near-linear cobalt coordination geometry.

Original language	English
Pages (from-to)	2118-2121
Number of pages	4
Journal	Organometallics
Volume	34
Issue number	11
DOIs	https://doi.org/10.1021/om501233f
Publication status	Published - 8 Jun 2015
Externally published	Yes

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10.1021/om501233f

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title = "Low-Coordinate Cobalt(I) Complexes Stabilized by an Extremely Bulky Amide Ligand",

abstract = "A series of low-coordinate, high-spin, mono- and dinuclear cobalt(I) complexes bearing an extremely bulky amide (La″ = N(Ar∗)(SiPh3); Ar∗ = C6H2{C(H)Ph2}2Me-2,6,4) ligand have been synthesized and characterized. These include the first example of a neutral two-coordinate cobalt(I) complex, [La″Co(IPriMe)] (IPriMe =:C{N(Pri)C(Me)}2), which has a near-linear cobalt coordination geometry.",

author = "Jamie Hicks and Cameron Jones",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

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AU - Jones, Cameron

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N2 - A series of low-coordinate, high-spin, mono- and dinuclear cobalt(I) complexes bearing an extremely bulky amide (La″ = N(Ar∗)(SiPh3); Ar∗ = C6H2{C(H)Ph2}2Me-2,6,4) ligand have been synthesized and characterized. These include the first example of a neutral two-coordinate cobalt(I) complex, [La″Co(IPriMe)] (IPriMe =:C{N(Pri)C(Me)}2), which has a near-linear cobalt coordination geometry.

AB - A series of low-coordinate, high-spin, mono- and dinuclear cobalt(I) complexes bearing an extremely bulky amide (La″ = N(Ar∗)(SiPh3); Ar∗ = C6H2{C(H)Ph2}2Me-2,6,4) ligand have been synthesized and characterized. These include the first example of a neutral two-coordinate cobalt(I) complex, [La″Co(IPriMe)] (IPriMe =:C{N(Pri)C(Me)}2), which has a near-linear cobalt coordination geometry.

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IS - 11

ER -

Low-Coordinate Cobalt(I) Complexes Stabilized by an Extremely Bulky Amide Ligand

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