Abstract
The angular dependence of the profile broadening of Na, Li, and F during secondary ion mass
spectrometry depth profiling was investigated in either n- or p-type Si using 10 keV O2
1 or N2 1 bombardment. The electric field-induced segregation of Na and Li at the SiO2/Si interface increased exponentially for O2 1 bombardment below ;27°, whereas a N2 1 beam provided better depth
resolution. The N2 1 beam-induced profile broadening of Li was higher in the low resistivity n-type
Si than in the high resistivity p-type Si for bombardment conditions producing a nitride layer at the surface. This behavior was characteristic of the field-induced segregation of Li at the SiNy/Si
interface. Profiling below the critical angle for oxide formation resulted in the antisegregation of F
into the SiO2 layer and gave sharper profiles. The decay length of F decreased exponentially with
the surface charging of the SiO2 layer. By contrast, broader profiles were obtained under N2
1 bombardment for the same impact angles. © 2001 American Vacuum Society.
spectrometry depth profiling was investigated in either n- or p-type Si using 10 keV O2
1 or N2 1 bombardment. The electric field-induced segregation of Na and Li at the SiO2/Si interface increased exponentially for O2 1 bombardment below ;27°, whereas a N2 1 beam provided better depth
resolution. The N2 1 beam-induced profile broadening of Li was higher in the low resistivity n-type
Si than in the high resistivity p-type Si for bombardment conditions producing a nitride layer at the surface. This behavior was characteristic of the field-induced segregation of Li at the SiNy/Si
interface. Profiling below the critical angle for oxide formation resulted in the antisegregation of F
into the SiO2 layer and gave sharper profiles. The decay length of F decreased exponentially with
the surface charging of the SiO2 layer. By contrast, broader profiles were obtained under N2
1 bombardment for the same impact angles. © 2001 American Vacuum Society.
Original language | English |
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Pages (from-to) | 893-898 |
Number of pages | 6 |
Journal | Journal of Vacuum Science and Technology A |
Volume | 19 |
Issue number | 3 |
DOIs | |
Publication status | Published - 2001 |