Mercuriophosphaalkene-P complexes: Crystal structure of [Ru{P(=CHBut)HgC5H4Fe(η-C5H 5)}Cl2(CO)(PPh3)2]

Anthony F. Hill; Cameron Jones; Andrew J.P. White; David J. Williams; James D.E.T. Wilton-Ely

doi:10.1039/a801513i

Mercuriophosphaalkene-P complexes: Crystal structure of [Ru{P(=CHBu^t)HgC₅H₄Fe(η-C₅H ₅)}Cl₂(CO)(PPh₃)₂]

Anthony F. Hill^*, Cameron Jones, Andrew J.P. White, David J. Williams, James D.E.T. Wilton-Ely

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Stable complexes of mercuriophosphaalkenes have resulted from the addition of organomercury halides to the Ru-P bond of [Ru(P=CHBu^t)Cl(CA)(PPh₃)₂] (A = O or S), including the structurally characterised complex [Ru{P(=CHBu^t)HgC₅H₄-Fe(η-C ₅H₅)}Cl₂(CO)(PPh₃)₂].

Original language	English
Pages (from-to)	1419-1420
Number of pages	2
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	9
DOIs	https://doi.org/10.1039/a801513i
Publication status	Published - 7 May 1998
Externally published	Yes

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title = "Mercuriophosphaalkene-P complexes: Crystal structure of [Ru{P(=CHBut)HgC5H4Fe(η-C5H 5)}Cl2(CO)(PPh3)2]",

abstract = "Stable complexes of mercuriophosphaalkenes have resulted from the addition of organomercury halides to the Ru-P bond of [Ru(P=CHBut)Cl(CA)(PPh3)2] (A = O or S), including the structurally characterised complex [Ru{P(=CHBut)HgC5H4-Fe(η-C 5H5)}Cl2(CO)(PPh3)2].",

author = "Hill, {Anthony F.} and Cameron Jones and White, {Andrew J.P.} and Williams, {David J.} and Wilton-Ely, {James D.E.T.}",

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T2 - Crystal structure of [Ru{P(=CHBut)HgC5H4Fe(η-C5H 5)}Cl2(CO)(PPh3)2]

AU - Hill, Anthony F.

AU - Jones, Cameron

AU - White, Andrew J.P.

AU - Williams, David J.

AU - Wilton-Ely, James D.E.T.

PY - 1998/5/7

Y1 - 1998/5/7

N2 - Stable complexes of mercuriophosphaalkenes have resulted from the addition of organomercury halides to the Ru-P bond of [Ru(P=CHBut)Cl(CA)(PPh3)2] (A = O or S), including the structurally characterised complex [Ru{P(=CHBut)HgC5H4-Fe(η-C 5H5)}Cl2(CO)(PPh3)2].

AB - Stable complexes of mercuriophosphaalkenes have resulted from the addition of organomercury halides to the Ru-P bond of [Ru(P=CHBut)Cl(CA)(PPh3)2] (A = O or S), including the structurally characterised complex [Ru{P(=CHBut)HgC5H4-Fe(η-C 5H5)}Cl2(CO)(PPh3)2].

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DO - 10.1039/a801513i

M3 - Article

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Mercuriophosphaalkene-P complexes: Crystal structure of [Ru{P(=CHBu^t)HgC₅H₄Fe(η-C₅H ₅)}Cl₂(CO)(PPh₃)₂]

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