Metal Actuated Ring Translocation Switches in Water

Hang Yin; Roselyne Rosas; Didier Gigmes; Olivier Ouari; Ruibing Wang; Anthony Kermagoret; David Bardelang

doi:10.1021/acs.orglett.8b01019

Metal Actuated Ring Translocation Switches in Water

Hang Yin, Roselyne Rosas, Didier Gigmes, Olivier Ouari, Ruibing Wang^*, Anthony Kermagoret, David Bardelang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Among a series of metal ions in water, silver is the only one to remotely and reversibly switch cucurbit[7]uril (CB[7]) movements (translocation or uptake) on a rigid and linear three-station viologen-phenylene-imidazole (V-P-I) derivative, avoiding undesired pH actuation. ¹H NMR, UV-vis spectroscopy, mass spectrometry, ITC, and modeling were combined to show that ring translocation or uptake along a molecular thread is possible in water by Ag⁺ as a metal stimulus.

Original language	English
Pages (from-to)	3187-3191
Number of pages	5
Journal	Organic Letters
Volume	20
Issue number	11
DOIs	https://doi.org/10.1021/acs.orglett.8b01019
Publication status	Published - 1 Jun 2018
Externally published	Yes

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title = "Metal Actuated Ring Translocation Switches in Water",

abstract = "Among a series of metal ions in water, silver is the only one to remotely and reversibly switch cucurbit[7]uril (CB[7]) movements (translocation or uptake) on a rigid and linear three-station viologen-phenylene-imidazole (V-P-I) derivative, avoiding undesired pH actuation. 1H NMR, UV-vis spectroscopy, mass spectrometry, ITC, and modeling were combined to show that ring translocation or uptake along a molecular thread is possible in water by Ag+ as a metal stimulus.",

author = "Hang Yin and Roselyne Rosas and Didier Gigmes and Olivier Ouari and Ruibing Wang and Anthony Kermagoret and David Bardelang",

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AU - Yin, Hang

AU - Rosas, Roselyne

AU - Gigmes, Didier

AU - Ouari, Olivier

AU - Wang, Ruibing

AU - Kermagoret, Anthony

AU - Bardelang, David

PY - 2018/6/1

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N2 - Among a series of metal ions in water, silver is the only one to remotely and reversibly switch cucurbit[7]uril (CB[7]) movements (translocation or uptake) on a rigid and linear three-station viologen-phenylene-imidazole (V-P-I) derivative, avoiding undesired pH actuation. 1H NMR, UV-vis spectroscopy, mass spectrometry, ITC, and modeling were combined to show that ring translocation or uptake along a molecular thread is possible in water by Ag+ as a metal stimulus.

AB - Among a series of metal ions in water, silver is the only one to remotely and reversibly switch cucurbit[7]uril (CB[7]) movements (translocation or uptake) on a rigid and linear three-station viologen-phenylene-imidazole (V-P-I) derivative, avoiding undesired pH actuation. 1H NMR, UV-vis spectroscopy, mass spectrometry, ITC, and modeling were combined to show that ring translocation or uptake along a molecular thread is possible in water by Ag+ as a metal stimulus.

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JO - Organic Letters

JF - Organic Letters

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Metal Actuated Ring Translocation Switches in Water

Abstract

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