Metal coordination of phosphoniocarbynes

Chee S. Onn; Anthony F. Hill; Angus Olding

doi:10.1039/d0dt02737e

Metal coordination of phosphoniocarbynes

Chee S. Onn, Anthony F. Hill^*, Angus Olding

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Heterobi- and tetrametallic phosphoniocarbyne bridged complexes [WAu(μ-CPMe₂Ph)Cl(CO)₂(Tp*)]⁺(Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate), [W₂Cu₂(μ-CPMe₂Ph)₂(μ-Cl)₂(CO)₄(Tp*)₂]²⁺and [WPt(μ-CPMe₂Ph)(COD)(CO)₂(Tp*)]⁺(COD = 1,5-cyclo-octadiene) arise from the reactions of the mononuclear terminal phosphoniocarbyne [W(CPMe₂Ph)(CO)₂(Tp*)]PF₆with [AuCl(THT)] (THT = tetrahydrothiophene), [CuCl(SMe₂)] and [Pt(nbe)₃] (nbe = norbornene) in the presence of COD. The COD ligand in [WPt(μ-CPMe₂Ph)(COD)(CO)₂(Tp*)]⁺is labile and readily replaced by isonitriles to provide [WPt(μ-CPMe₂Ph)(CNR)₂(CO)₂(Tp*)]⁺(R =^tBu, C₆H₂Me₃-2,4,6) with retention of the tungstaplatinacyclopropene core, the bonding within which was computationally interrogated.

Original language	English
Pages (from-to)	12731-12741
Number of pages	11
Journal	Dalton Transactions
Volume	49
Issue number	36
DOIs	https://doi.org/10.1039/d0dt02737e
Publication status	Published - 28 Sept 2020

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@article{2264893073bb4810a8704cd12a3a44a7,

title = "Metal coordination of phosphoniocarbynes",

abstract = "Heterobi- and tetrametallic phosphoniocarbyne bridged complexes [WAu(μ-CPMe2Ph)Cl(CO)2(Tp*)]+(Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate), [W2Cu2(μ-CPMe2Ph)2(μ-Cl)2(CO)4(Tp*)2]2+and [WPt(μ-CPMe2Ph)(COD)(CO)2(Tp*)]+(COD = 1,5-cyclo-octadiene) arise from the reactions of the mononuclear terminal phosphoniocarbyne [W(CPMe2Ph)(CO)2(Tp*)]PF6with [AuCl(THT)] (THT = tetrahydrothiophene), [CuCl(SMe2)] and [Pt(nbe)3] (nbe = norbornene) in the presence of COD. The COD ligand in [WPt(μ-CPMe2Ph)(COD)(CO)2(Tp*)]+is labile and readily replaced by isonitriles to provide [WPt(μ-CPMe2Ph)(CNR)2(CO)2(Tp*)]+(R =tBu, C6H2Me3-2,4,6) with retention of the tungstaplatinacyclopropene core, the bonding within which was computationally interrogated.",

author = "Onn, {Chee S.} and Hill, {Anthony F.} and Angus Olding",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2020.",

year = "2020",

month = sep,

day = "28",

doi = "10.1039/d0dt02737e",

language = "English",

volume = "49",

pages = "12731--12741",

journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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T1 - Metal coordination of phosphoniocarbynes

AU - Onn, Chee S.

AU - Hill, Anthony F.

AU - Olding, Angus

PY - 2020/9/28

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N2 - Heterobi- and tetrametallic phosphoniocarbyne bridged complexes [WAu(μ-CPMe2Ph)Cl(CO)2(Tp*)]+(Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate), [W2Cu2(μ-CPMe2Ph)2(μ-Cl)2(CO)4(Tp*)2]2+and [WPt(μ-CPMe2Ph)(COD)(CO)2(Tp*)]+(COD = 1,5-cyclo-octadiene) arise from the reactions of the mononuclear terminal phosphoniocarbyne [W(CPMe2Ph)(CO)2(Tp*)]PF6with [AuCl(THT)] (THT = tetrahydrothiophene), [CuCl(SMe2)] and [Pt(nbe)3] (nbe = norbornene) in the presence of COD. The COD ligand in [WPt(μ-CPMe2Ph)(COD)(CO)2(Tp*)]+is labile and readily replaced by isonitriles to provide [WPt(μ-CPMe2Ph)(CNR)2(CO)2(Tp*)]+(R =tBu, C6H2Me3-2,4,6) with retention of the tungstaplatinacyclopropene core, the bonding within which was computationally interrogated.

AB - Heterobi- and tetrametallic phosphoniocarbyne bridged complexes [WAu(μ-CPMe2Ph)Cl(CO)2(Tp*)]+(Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate), [W2Cu2(μ-CPMe2Ph)2(μ-Cl)2(CO)4(Tp*)2]2+and [WPt(μ-CPMe2Ph)(COD)(CO)2(Tp*)]+(COD = 1,5-cyclo-octadiene) arise from the reactions of the mononuclear terminal phosphoniocarbyne [W(CPMe2Ph)(CO)2(Tp*)]PF6with [AuCl(THT)] (THT = tetrahydrothiophene), [CuCl(SMe2)] and [Pt(nbe)3] (nbe = norbornene) in the presence of COD. The COD ligand in [WPt(μ-CPMe2Ph)(COD)(CO)2(Tp*)]+is labile and readily replaced by isonitriles to provide [WPt(μ-CPMe2Ph)(CNR)2(CO)2(Tp*)]+(R =tBu, C6H2Me3-2,4,6) with retention of the tungstaplatinacyclopropene core, the bonding within which was computationally interrogated.

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U2 - 10.1039/d0dt02737e

DO - 10.1039/d0dt02737e

M3 - Article

SN - 1477-9226

VL - 49

SP - 12731

EP - 12741

JO - Dalton Transactions

JF - Dalton Transactions

IS - 36

ER -

Metal coordination of phosphoniocarbynes

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