Metallaboratranes: The M→B dative bond as a ligand activating function in the phosphaboration of carbon monosulfide

Ian R. Crossley; Anthony F. Hill; Anthony C. Willis

doi:10.1021/om700433q

Metallaboratranes: The M→B dative bond as a ligand activating function in the phosphaboration of carbon monosulfide

Ian R. Crossley, Anthony F. Hill^*, Anthony C. Willis

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

70 Citations (Scopus)

Abstract

The reaction of Na[H₂B(mt)₂] (mt = methimazolyl) with [RhCl(CO)(PPh₃)₂] proceeds via simple metathesis to provide the complex [Rh(CO)(PPh₃){H₂B(mt)₂}]; however, with [RhCl(CS)(PPh₃)₂] C,C-phosphaboration of the thiocarbonyl ligand occurs, with formation of the novel cage complex [RhH-(PPh₃){η²(C,S), κ²S′, S″-SC(PPh₃)BH(mt)₂}].

Original language	English
Pages (from-to)	3891-3895
Number of pages	5
Journal	Organometallics
Volume	26
Issue number	16
DOIs	https://doi.org/10.1021/om700433q
Publication status	Published - 30 Jul 2007

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@article{746264175d08466d91532951964d5e09,

title = "Metallaboratranes: The M→B dative bond as a ligand activating function in the phosphaboration of carbon monosulfide",

abstract = "The reaction of Na[H2B(mt)2] (mt = methimazolyl) with [RhCl(CO)(PPh3)2] proceeds via simple metathesis to provide the complex [Rh(CO)(PPh3){H2B(mt)2}]; however, with [RhCl(CS)(PPh3)2] C,C-phosphaboration of the thiocarbonyl ligand occurs, with formation of the novel cage complex [RhH-(PPh3){η2(C,S), κ2S′, S″-SC(PPh3)BH(mt)2}].",

author = "Crossley, {Ian R.} and Hill, {Anthony F.} and Willis, {Anthony C.}",

year = "2007",

month = jul,

day = "30",

doi = "10.1021/om700433q",

language = "English",

volume = "26",

pages = "3891--3895",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "16",

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T1 - Metallaboratranes

T2 - The M→B dative bond as a ligand activating function in the phosphaboration of carbon monosulfide

AU - Crossley, Ian R.

AU - Hill, Anthony F.

AU - Willis, Anthony C.

PY - 2007/7/30

Y1 - 2007/7/30

N2 - The reaction of Na[H2B(mt)2] (mt = methimazolyl) with [RhCl(CO)(PPh3)2] proceeds via simple metathesis to provide the complex [Rh(CO)(PPh3){H2B(mt)2}]; however, with [RhCl(CS)(PPh3)2] C,C-phosphaboration of the thiocarbonyl ligand occurs, with formation of the novel cage complex [RhH-(PPh3){η2(C,S), κ2S′, S″-SC(PPh3)BH(mt)2}].

AB - The reaction of Na[H2B(mt)2] (mt = methimazolyl) with [RhCl(CO)(PPh3)2] proceeds via simple metathesis to provide the complex [Rh(CO)(PPh3){H2B(mt)2}]; however, with [RhCl(CS)(PPh3)2] C,C-phosphaboration of the thiocarbonyl ligand occurs, with formation of the novel cage complex [RhH-(PPh3){η2(C,S), κ2S′, S″-SC(PPh3)BH(mt)2}].

UR - http://www.scopus.com/inward/record.url?scp=34547797363&partnerID=8YFLogxK

U2 - 10.1021/om700433q

DO - 10.1021/om700433q

M3 - Article

SN - 0276-7333

VL - 26

SP - 3891

EP - 3895

JO - Organometallics

JF - Organometallics

IS - 16

ER -

Metallaboratranes: The M→B dative bond as a ligand activating function in the phosphaboration of carbon monosulfide

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