Metallaoxetene Formation By Coupling of Carbamoyl and Difluorocarbene Ligands

Stephen Anderson; Anthony F. Hill; Alexandra M.Z. Slawin; David J. Williams

doi:10.1039/c39930000266

Metallaoxetene Formation By Coupling of Carbamoyl and Difluorocarbene Ligands

Stephen Anderson, Anthony F. Hill, Alexandra M.Z. Slawin, David J. Williams

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The reaction of the carbamoyl complex [Fe{C(=O)NPri2}CF3(CO)2 (PPh3)] with potassium hydrotris(pyrazol-1-yl)borate provides the structurally characterised ferraoxetene [Fe{CF2OC(NPri2)}(CO){HB(pz)3}] (pz = pyrazol-1-yl), presumably via coupling of the carbamoyl ligand with a difluorocarbene intermediate

Original language	English
Pages (from-to)	266-267
Number of pages	2
Journal	Chemical Communications
Issue number	3
DOIs	https://doi.org/10.1039/c39930000266
Publication status	Published - 7 Feb 1993
Externally published	Yes

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title = "Metallaoxetene Formation By Coupling of Carbamoyl and Difluorocarbene Ligands",

abstract = "The reaction of the carbamoyl complex [Fe{C(=O)NPri2}CF3(CO)2 (PPh3)] with potassium hydrotris(pyrazol-1-yl)borate provides the structurally characterised ferraoxetene [Fe{CF2OC(NPri2)}(CO){HB(pz)3}] (pz = pyrazol-1-yl), presumably via coupling of the carbamoyl ligand with a difluorocarbene intermediate",

keywords = "Complexes",

author = "Stephen Anderson and Hill, {Anthony F.} and Slawin, {Alexandra M.Z.} and Williams, {David J.}",

year = "1993",

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doi = "10.1039/c39930000266",

language = "English",

pages = "266--267",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Metallaoxetene Formation By Coupling of Carbamoyl and Difluorocarbene Ligands

AU - Anderson, Stephen

AU - Hill, Anthony F.

AU - Slawin, Alexandra M.Z.

AU - Williams, David J.

PY - 1993/2/7

Y1 - 1993/2/7

N2 - The reaction of the carbamoyl complex [Fe{C(=O)NPri2}CF3(CO)2 (PPh3)] with potassium hydrotris(pyrazol-1-yl)borate provides the structurally characterised ferraoxetene [Fe{CF2OC(NPri2)}(CO){HB(pz)3}] (pz = pyrazol-1-yl), presumably via coupling of the carbamoyl ligand with a difluorocarbene intermediate

AB - The reaction of the carbamoyl complex [Fe{C(=O)NPri2}CF3(CO)2 (PPh3)] with potassium hydrotris(pyrazol-1-yl)borate provides the structurally characterised ferraoxetene [Fe{CF2OC(NPri2)}(CO){HB(pz)3}] (pz = pyrazol-1-yl), presumably via coupling of the carbamoyl ligand with a difluorocarbene intermediate

KW - Complexes

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U2 - 10.1039/c39930000266

DO - 10.1039/c39930000266

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EP - 267

JO - Chemical Communications

JF - Chemical Communications

IS - 3

ER -

Metallaoxetene Formation By Coupling of Carbamoyl and Difluorocarbene Ligands

Abstract

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