TY - JOUR
T1 - Metallaoxetene Formation By Coupling of Carbamoyl and Difluorocarbene Ligands
AU - Anderson, Stephen
AU - Hill, Anthony F.
AU - Slawin, Alexandra M.Z.
AU - Williams, David J.
PY - 1993/2/7
Y1 - 1993/2/7
N2 - The reaction of the carbamoyl complex [Fe{C(=O)NPri2}CF3(CO)2 (PPh3)] with potassium hydrotris(pyrazol-1-yl)borate provides the structurally characterised ferraoxetene [Fe{CF2OC(NPri2)}(CO){HB(pz)3}] (pz = pyrazol-1-yl), presumably via coupling of the carbamoyl ligand with a difluorocarbene intermediate
AB - The reaction of the carbamoyl complex [Fe{C(=O)NPri2}CF3(CO)2 (PPh3)] with potassium hydrotris(pyrazol-1-yl)borate provides the structurally characterised ferraoxetene [Fe{CF2OC(NPri2)}(CO){HB(pz)3}] (pz = pyrazol-1-yl), presumably via coupling of the carbamoyl ligand with a difluorocarbene intermediate
KW - Complexes
UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:A1993KL90400030&DestLinkType=FullRecord&DestApp=WOS_CPL
UR - https://www.scopus.com/pages/publications/37049069795
U2 - 10.1039/c39930000266
DO - 10.1039/c39930000266
M3 - Article
SN - 1359-7345
SP - 266
EP - 267
JO - Chemical Communications
JF - Chemical Communications
IS - 3
ER -