Metallathiirenes. 4. Thioaroyl complexes of molybdenum(II) and tungsten(II)

Darren J. Cook; Anthony F. Hill

doi:10.1021/om030261s

Metallathiirenes. 4. Thioaroyl complexes of molybdenum(II) and tungsten(II)

Darren J. Cook, Anthony F. Hill^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

Synthetic routes to a range of thioaroyl complexes of tungsten and molybdenum were reported. The synthesis precludes hyperconjugation into the metallathiirene system which reduces the stability but significantly enhances the reactivity and synthetic utility. Results showed that methylthiirane can be used as an effective sulfur transfer reagent too.

Original language	English
Pages (from-to)	3502-3512
Number of pages	11
Journal	Organometallics
Volume	22
Issue number	17
DOIs	https://doi.org/10.1021/om030261s
Publication status	Published - 18 Aug 2003

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abstract = "Synthetic routes to a range of thioaroyl complexes of tungsten and molybdenum were reported. The synthesis precludes hyperconjugation into the metallathiirene system which reduces the stability but significantly enhances the reactivity and synthetic utility. Results showed that methylthiirane can be used as an effective sulfur transfer reagent too.",

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AB - Synthetic routes to a range of thioaroyl complexes of tungsten and molybdenum were reported. The synthesis precludes hyperconjugation into the metallathiirene system which reduces the stability but significantly enhances the reactivity and synthetic utility. Results showed that methylthiirane can be used as an effective sulfur transfer reagent too.

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Metallathiirenes. 4. Thioaroyl complexes of molybdenum(II) and tungsten(II)

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