Metallathiirenes. 5.1 Bis- and Tris(methimazolyl)borato Thiocarbamoyl Complexes of Molybdenum(II)

Mark R.St J. Foreman; Anthony F. Hill; Never Tshabang; Andrew J.P. White; David J. Williams

doi:10.1021/om030584o

Metallathiirenes. 5.¹ Bis- and Tris(methimazolyl)borato Thiocarbamoyl Complexes of Molybdenum(II)

Mark R.St J. Foreman, Anthony F. Hill^*, Never Tshabang, Andrew J.P. White, David J. Williams

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

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Abstract

The synthesis of the molybdenum thiocarbamoyl complexes was presented. The complexes were obtained from the reactions of [Mo(η²-SCNMe ₂)Cl(CO)₂(tmeda)] and Na[H_nB(mt) _4-n] or via reactions of the salts Na[Mo(CO)_2+n{H _nB(mt)_4-n}] with Me₂NCSCl. For n=2, the complex displayed agostic B-H-Mo coordination in solution and the solid state. The B-H hydrogen atoms, were located and refined freely to provide B-H(1) and Mo-H(1) separations of 1.22(4) and 1.92(4) Å respectively.

Original language	English
Pages (from-to)	5593-5596
Number of pages	4
Journal	Organometallics
Volume	22
Issue number	26
DOIs	https://doi.org/10.1021/om030584o
Publication status	Published - 22 Dec 2003

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title = "Metallathiirenes. 5.1 Bis- and Tris(methimazolyl)borato Thiocarbamoyl Complexes of Molybdenum(II)",

abstract = "The synthesis of the molybdenum thiocarbamoyl complexes was presented. The complexes were obtained from the reactions of [Mo(η2-SCNMe 2)Cl(CO)2(tmeda)] and Na[HnB(mt) 4-n] or via reactions of the salts Na[Mo(CO)2+n{H nB(mt)4-n}] with Me2NCSCl. For n=2, the complex displayed agostic B-H-Mo coordination in solution and the solid state. The B-H hydrogen atoms, were located and refined freely to provide B-H(1) and Mo-H(1) separations of 1.22(4) and 1.92(4) {\AA} respectively.",

author = "Foreman, {Mark R.St J.} and Hill, {Anthony F.} and Never Tshabang and White, {Andrew J.P.} and Williams, {David J.}",

year = "2003",

month = dec,

day = "22",

doi = "10.1021/om030584o",

language = "English",

volume = "22",

pages = "5593--5596",

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TY - JOUR

T1 - Metallathiirenes. 5.1 Bis- and Tris(methimazolyl)borato Thiocarbamoyl Complexes of Molybdenum(II)

AU - Foreman, Mark R.St J.

AU - Hill, Anthony F.

AU - Tshabang, Never

AU - White, Andrew J.P.

AU - Williams, David J.

PY - 2003/12/22

Y1 - 2003/12/22

N2 - The synthesis of the molybdenum thiocarbamoyl complexes was presented. The complexes were obtained from the reactions of [Mo(η2-SCNMe 2)Cl(CO)2(tmeda)] and Na[HnB(mt) 4-n] or via reactions of the salts Na[Mo(CO)2+n{H nB(mt)4-n}] with Me2NCSCl. For n=2, the complex displayed agostic B-H-Mo coordination in solution and the solid state. The B-H hydrogen atoms, were located and refined freely to provide B-H(1) and Mo-H(1) separations of 1.22(4) and 1.92(4) Å respectively.

AB - The synthesis of the molybdenum thiocarbamoyl complexes was presented. The complexes were obtained from the reactions of [Mo(η2-SCNMe 2)Cl(CO)2(tmeda)] and Na[HnB(mt) 4-n] or via reactions of the salts Na[Mo(CO)2+n{H nB(mt)4-n}] with Me2NCSCl. For n=2, the complex displayed agostic B-H-Mo coordination in solution and the solid state. The B-H hydrogen atoms, were located and refined freely to provide B-H(1) and Mo-H(1) separations of 1.22(4) and 1.92(4) Å respectively.

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U2 - 10.1021/om030584o

DO - 10.1021/om030584o

M3 - Article

SN - 0276-7333

VL - 22

SP - 5593

EP - 5596

JO - Organometallics

JF - Organometallics

IS - 26

ER -

Metallathiirenes. 5.¹ Bis- and Tris(methimazolyl)borato Thiocarbamoyl Complexes of Molybdenum(II)

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