Abstract
Three isostructural interwoven 3,4-connected mesoporous metal-organic frameworks of pto-a topology (UTSA-28-Cu, UTSA-28-Zn, and UTSA-28-Mn) were synthesized and structurally characterized. Because of their metastable nature, their gas sorption properties are highly dependent on the metal ions and activation profiles. The most stable, UTSA-28a-Cu, exhibits promising gas storage and separation capacities.
| Original language | English |
|---|---|
| Pages (from-to) | 11580-11584 |
| Number of pages | 5 |
| Journal | Inorganic Chemistry |
| Volume | 52 |
| Issue number | 19 |
| DOIs | |
| Publication status | Published - 7 Oct 2013 |
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