Mimicking enzymatic systems: Modulation of the performance of polymeric organocatalysts by ion-specific effects

Yun Xu; Zan Hua; Jian Zhang; Jun Yang; Zhonglin Cao; Dongyang Zhang; Lingxin He; Vincent S.J. Craig; Guangzhao Zhang; Guangming Liu

doi:10.1039/c5cc09959e

Mimicking enzymatic systems: Modulation of the performance of polymeric organocatalysts by ion-specific effects

Yun Xu, Zan Hua, Jian Zhang, Jun Yang, Zhonglin Cao, Dongyang Zhang, Lingxin He, Vincent S.J. Craig, Guangzhao Zhang, Guangming Liu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Like natural enzymatic systems, our study has demonstrated that the activity of the polymeric organocatalysts can be modulated by ion-specific effects via the combination of anion-specific salting-in/out effects and anion-specific polarization of hydrogen bonding induced stabilization of the transition state.

Original language	English
Pages (from-to)	3392-3395
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	16
DOIs	https://doi.org/10.1039/c5cc09959e
Publication status	Published - 2016

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title = "Mimicking enzymatic systems: Modulation of the performance of polymeric organocatalysts by ion-specific effects",

abstract = "Like natural enzymatic systems, our study has demonstrated that the activity of the polymeric organocatalysts can be modulated by ion-specific effects via the combination of anion-specific salting-in/out effects and anion-specific polarization of hydrogen bonding induced stabilization of the transition state.",

author = "Yun Xu and Zan Hua and Jian Zhang and Jun Yang and Zhonglin Cao and Dongyang Zhang and Lingxin He and Craig, {Vincent S.J.} and Guangzhao Zhang and Guangming Liu",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

doi = "10.1039/c5cc09959e",

language = "English",

volume = "52",

pages = "3392--3395",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "16",

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TY - JOUR

T1 - Mimicking enzymatic systems

T2 - Modulation of the performance of polymeric organocatalysts by ion-specific effects

AU - Xu, Yun

AU - Hua, Zan

AU - Zhang, Jian

AU - Yang, Jun

AU - Cao, Zhonglin

AU - Zhang, Dongyang

AU - He, Lingxin

AU - Craig, Vincent S.J.

AU - Zhang, Guangzhao

AU - Liu, Guangming

PY - 2016

Y1 - 2016

N2 - Like natural enzymatic systems, our study has demonstrated that the activity of the polymeric organocatalysts can be modulated by ion-specific effects via the combination of anion-specific salting-in/out effects and anion-specific polarization of hydrogen bonding induced stabilization of the transition state.

AB - Like natural enzymatic systems, our study has demonstrated that the activity of the polymeric organocatalysts can be modulated by ion-specific effects via the combination of anion-specific salting-in/out effects and anion-specific polarization of hydrogen bonding induced stabilization of the transition state.

UR - http://www.scopus.com/inward/record.url?scp=84958794004&partnerID=8YFLogxK

U2 - 10.1039/c5cc09959e

DO - 10.1039/c5cc09959e

M3 - Article

SN - 1359-7345

VL - 52

SP - 3392

EP - 3395

JO - Chemical Communications

JF - Chemical Communications

IS - 16

ER -

Mimicking enzymatic systems: Modulation of the performance of polymeric organocatalysts by ion-specific effects

Abstract

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