Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity

Ayesha Naeem; Valeska P. Ting; Ulrich Hintermair; Mi Tian; Richard Telford; Saaiba Halim; Harriott Nowell; Małgorzata Hołyńska; Simon J. Teat; Ian J. Scowen; Sanjit Nayak

doi:10.1039/c6cc03787a

Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity

Ayesha Naeem, Valeska P. Ting, Ulrich Hintermair, Mi Tian, Richard Telford, Saaiba Halim, Harriott Nowell, Małgorzata Hołyńska, Simon J. Teat, Ian J. Scowen, Sanjit Nayak^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

Three highly porous Zr(iv)-based metal-organic frameworks, UBMOF-8, UBMOF-9, and UBMOF-31, were synthesized by using 2,2′-diamino-4,4′-stilbenedicarboxylic acid, 4,4′-stilbenedicarboxylic acid, and combination of both linkers, respectively. The mixed-linker UBMOF-31 showed excellent hydrogen uptake of 4.9 wt% and high selectivity for adsorption of CO₂ over N₂ with high thermal stability and moderate water stability with permanent porosity and surface area of 2552 m² g^-1.

Original language	English
Pages (from-to)	7826-7829
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	50
DOIs	https://doi.org/10.1039/c6cc03787a
Publication status	Published - 2016
Externally published	Yes

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title = "Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity",

abstract = "Three highly porous Zr(iv)-based metal-organic frameworks, UBMOF-8, UBMOF-9, and UBMOF-31, were synthesized by using 2,2′-diamino-4,4′-stilbenedicarboxylic acid, 4,4′-stilbenedicarboxylic acid, and combination of both linkers, respectively. The mixed-linker UBMOF-31 showed excellent hydrogen uptake of 4.9 wt% and high selectivity for adsorption of CO2 over N2 with high thermal stability and moderate water stability with permanent porosity and surface area of 2552 m2 g-1.",

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year = "2016",

doi = "10.1039/c6cc03787a",

language = "English",

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T1 - Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity

AU - Naeem, Ayesha

AU - Ting, Valeska P.

AU - Hintermair, Ulrich

AU - Tian, Mi

AU - Telford, Richard

AU - Halim, Saaiba

AU - Nowell, Harriott

AU - Hołyńska, Małgorzata

AU - Teat, Simon J.

AU - Scowen, Ian J.

AU - Nayak, Sanjit

PY - 2016

Y1 - 2016

N2 - Three highly porous Zr(iv)-based metal-organic frameworks, UBMOF-8, UBMOF-9, and UBMOF-31, were synthesized by using 2,2′-diamino-4,4′-stilbenedicarboxylic acid, 4,4′-stilbenedicarboxylic acid, and combination of both linkers, respectively. The mixed-linker UBMOF-31 showed excellent hydrogen uptake of 4.9 wt% and high selectivity for adsorption of CO2 over N2 with high thermal stability and moderate water stability with permanent porosity and surface area of 2552 m2 g-1.

AB - Three highly porous Zr(iv)-based metal-organic frameworks, UBMOF-8, UBMOF-9, and UBMOF-31, were synthesized by using 2,2′-diamino-4,4′-stilbenedicarboxylic acid, 4,4′-stilbenedicarboxylic acid, and combination of both linkers, respectively. The mixed-linker UBMOF-31 showed excellent hydrogen uptake of 4.9 wt% and high selectivity for adsorption of CO2 over N2 with high thermal stability and moderate water stability with permanent porosity and surface area of 2552 m2 g-1.

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U2 - 10.1039/c6cc03787a

DO - 10.1039/c6cc03787a

M3 - Article

SN - 1359-7345

VL - 52

SP - 7826

EP - 7829

JO - Chemical Communications

JF - Chemical Communications

IS - 50

ER -

Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity

Abstract

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