Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity

Ayesha Naeem; Valeska P. Ting; Ulrich Hintermair; Mi Tian; Richard Telford; Saaiba Halim; Harriott Nowell; Małgorzata Hołyńska; Simon J. Teat; Ian J. Scowen; Sanjit Nayak

doi:10.1039/c6cc03787a

Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity

Ayesha Naeem
, Valeska P. Ting
, Ulrich Hintermair
, Mi Tian
, Richard Telford
, Saaiba Halim
, Harriott Nowell
, Małgorzata Hołyńska
, Simon J. Teat
, Ian J. Scowen
, Sanjit Nayak^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

Three highly porous Zr(iv)-based metal-organic frameworks, UBMOF-8, UBMOF-9, and UBMOF-31, were synthesized by using 2,2′-diamino-4,4′-stilbenedicarboxylic acid, 4,4′-stilbenedicarboxylic acid, and combination of both linkers, respectively. The mixed-linker UBMOF-31 showed excellent hydrogen uptake of 4.9 wt% and high selectivity for adsorption of CO₂ over N₂ with high thermal stability and moderate water stability with permanent porosity and surface area of 2552 m² g^-1.

Original language	English
Pages (from-to)	7826-7829
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	50
DOIs	https://doi.org/10.1039/c6cc03787a
Publication status	Published - 2016
Externally published	Yes

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title = "Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity",

abstract = "Three highly porous Zr(iv)-based metal-organic frameworks, UBMOF-8, UBMOF-9, and UBMOF-31, were synthesized by using 2,2′-diamino-4,4′-stilbenedicarboxylic acid, 4,4′-stilbenedicarboxylic acid, and combination of both linkers, respectively. The mixed-linker UBMOF-31 showed excellent hydrogen uptake of 4.9 wt\% and high selectivity for adsorption of CO2 over N2 with high thermal stability and moderate water stability with permanent porosity and surface area of 2552 m2 g-1.",

author = "Ayesha Naeem and Ting, \{Valeska P.\} and Ulrich Hintermair and Mi Tian and Richard Telford and Saaiba Halim and Harriott Nowell and Ma{\l}gorzata Ho{\l}y{\'n}ska and Teat, \{Simon J.\} and Scowen, \{Ian J.\} and Sanjit Nayak",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6cc03787a",

language = "English",

volume = "52",

pages = "7826--7829",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity

AU - Naeem, Ayesha

AU - Ting, Valeska P.

AU - Hintermair, Ulrich

AU - Tian, Mi

AU - Telford, Richard

AU - Halim, Saaiba

AU - Nowell, Harriott

AU - Hołyńska, Małgorzata

AU - Teat, Simon J.

AU - Scowen, Ian J.

AU - Nayak, Sanjit

PY - 2016

Y1 - 2016

N2 - Three highly porous Zr(iv)-based metal-organic frameworks, UBMOF-8, UBMOF-9, and UBMOF-31, were synthesized by using 2,2′-diamino-4,4′-stilbenedicarboxylic acid, 4,4′-stilbenedicarboxylic acid, and combination of both linkers, respectively. The mixed-linker UBMOF-31 showed excellent hydrogen uptake of 4.9 wt% and high selectivity for adsorption of CO2 over N2 with high thermal stability and moderate water stability with permanent porosity and surface area of 2552 m2 g-1.

AB - Three highly porous Zr(iv)-based metal-organic frameworks, UBMOF-8, UBMOF-9, and UBMOF-31, were synthesized by using 2,2′-diamino-4,4′-stilbenedicarboxylic acid, 4,4′-stilbenedicarboxylic acid, and combination of both linkers, respectively. The mixed-linker UBMOF-31 showed excellent hydrogen uptake of 4.9 wt% and high selectivity for adsorption of CO2 over N2 with high thermal stability and moderate water stability with permanent porosity and surface area of 2552 m2 g-1.

UR - https://www.scopus.com/pages/publications/84975048886

U2 - 10.1039/c6cc03787a

DO - 10.1039/c6cc03787a

M3 - Article

SN - 1359-7345

VL - 52

SP - 7826

EP - 7829

JO - Chemical Communications

JF - Chemical Communications

IS - 50

ER -

Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity

Abstract

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