Mixed-metal cluster chemistry. 21. Synthesis and crystallographic and electrochemical studies of alkyne-coordinated group 6-iridium clusters linked by phenylenevinylene groups

Nigel T. Lucas; Eleni G.A. Notaras; Marie P. Cifuentes; Mark G. Humphrey

doi:10.1021/om020203r

Mixed-metal cluster chemistry. 21. Synthesis and crystallographic and electrochemical studies of alkyne-coordinated group 6-iridium clusters linked by phenylenevinylene groups

Nigel T. Lucas, Eleni G.A. Notaras, Marie P. Cifuentes, Mark G. Humphrey^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

Synthesis and crystallographic and electrochemical studies of alkyne-coordinated group 6-iridium clusters were discussed. Cyclic voltametry and ultraviolet-vis-near-infrared spectroscopy were used. Results showed that all compounds show a reversible/partially reversible oxidation which is followed by an irreversible oxidation process.

Original language	English
Pages (from-to)	284-301
Number of pages	18
Journal	Organometallics
Volume	22
Issue number	2
DOIs	https://doi.org/10.1021/om020203r
Publication status	Published - 20 Jan 2003

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10.1021/om020203r

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title = "Mixed-metal cluster chemistry. 21. Synthesis and crystallographic and electrochemical studies of alkyne-coordinated group 6-iridium clusters linked by phenylenevinylene groups",

abstract = "Synthesis and crystallographic and electrochemical studies of alkyne-coordinated group 6-iridium clusters were discussed. Cyclic voltametry and ultraviolet-vis-near-infrared spectroscopy were used. Results showed that all compounds show a reversible/partially reversible oxidation which is followed by an irreversible oxidation process.",

author = "Lucas, {Nigel T.} and Notaras, {Eleni G.A.} and Cifuentes, {Marie P.} and Humphrey, {Mark G.}",

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doi = "10.1021/om020203r",

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volume = "22",

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Mixed-metal cluster chemistry. 21. Synthesis and crystallographic and electrochemical studies of alkyne-coordinated group 6-iridium clusters linked by phenylenevinylene groups. / Lucas, Nigel T.; Notaras, Eleni G.A.; Cifuentes, Marie P. et al.
In: Organometallics, Vol. 22, No. 2, 20.01.2003, p. 284-301.

Research output: Contribution to journal › Article › peer-review

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T1 - Mixed-metal cluster chemistry. 21. Synthesis and crystallographic and electrochemical studies of alkyne-coordinated group 6-iridium clusters linked by phenylenevinylene groups

AU - Lucas, Nigel T.

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AU - Cifuentes, Marie P.

AU - Humphrey, Mark G.

PY - 2003/1/20

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N2 - Synthesis and crystallographic and electrochemical studies of alkyne-coordinated group 6-iridium clusters were discussed. Cyclic voltametry and ultraviolet-vis-near-infrared spectroscopy were used. Results showed that all compounds show a reversible/partially reversible oxidation which is followed by an irreversible oxidation process.

AB - Synthesis and crystallographic and electrochemical studies of alkyne-coordinated group 6-iridium clusters were discussed. Cyclic voltametry and ultraviolet-vis-near-infrared spectroscopy were used. Results showed that all compounds show a reversible/partially reversible oxidation which is followed by an irreversible oxidation process.

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IS - 2

ER -

Mixed-metal cluster chemistry. 21. Synthesis and crystallographic and electrochemical studies of alkyne-coordinated group 6-iridium clusters linked by phenylenevinylene groups

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