Mobile metal ion® analysis of european agricultural soils: Bioavailability, weathering, Geogenic patterns and anthropogenic anomalies

A. Mann; C. Reimann; P. De Caritat; N. Turner; M. Birke; S. Albanese; M. Andersson; R. Baritz; M. J. Batista; A. Bel-Lan; D. Cicchella; A. Demetriades; B. De Vivo; W. De Vos; E. Dinelli; M. Ďuriš; A. Dusza-Dobek; O. A. Eggen; M. Eklund; V. Ernstsen; K. Fabian; P. Filzmoser; D. Flight; S. Forrester; M. Fuchs; U. Fügedi; A. Gilucis; M. Gosar; V. Gregorauskiene; W. De Groot; A. Gulan; J. Halamić; E. Haslinger; P. Hayoz; R. Hoffmann; J. Hoogewerff; H. Hrvatovic; S. Husnjak; L. Janik; G. Jordan; M. Kaminari; J. Kirby; J. Kivisilla; V. Klos; F. Krone; P. Kwećko; L. Kuti; A. Ladenberger; A. Lima; J. Locutura; D. P. Lucivjansky; A. Mann; D. Mackovych; M. McLaughlin; B. I. Malyuk; R. Maquil; R. G. Meuli; G. Mol; P. Negrel; P. O’Connor; R. K. Oorts; R. T. Ottesen; A. Pasieczna; W. Petersell; S. Pfleiderer; M. Poňavič; S. Pramuka; C. Prazeres; U. Rauch; S. Radusinović; M. Sadeghi; I. Salpeteur; R. Scanlon; A. Schedl; A. J. Scheib; I. Schoeters; P. Šefčik; E. Sellersjö; F. Skopljak; I. Slaninka; A. Šorša; R. Srvkota; T. Stafilov; T. Tarvainen; V. Trendavilov; P. Valera; V. Verougstraete; D. Vidojević; A. Zissimos; Z. Zomeni

doi:10.1144/geochem2014-279

Mobile metal ion® analysis of european agricultural soils: Bioavailability, weathering, Geogenic patterns and anthropogenic anomalies

A. Mann^*, C. Reimann, P. De Caritat, N. Turner, M. Birke, S. Albanese, M. Andersson, R. Baritz, M. J. Batista, A. Bel-Lan, D. Cicchella, A. Demetriades, B. De Vivo, W. De Vos, E. Dinelli, M. Ďuriš, A. Dusza-Dobek, O. A. Eggen, M. Eklund, V. ErnstsenK. Fabian, P. Filzmoser, D. Flight, S. Forrester, M. Fuchs, U. Fügedi, A. Gilucis, M. Gosar, V. Gregorauskiene, W. De Groot, A. Gulan, J. Halamić, E. Haslinger, P. Hayoz, R. Hoffmann, J. Hoogewerff, H. Hrvatovic, S. Husnjak, L. Janik, G. Jordan, M. Kaminari, J. Kirby, J. Kivisilla, V. Klos, F. Krone, P. Kwećko, L. Kuti, A. Ladenberger, A. Lima, J. Locutura, D. P. Lucivjansky, A. Mann^*, D. Mackovych, M. McLaughlin, B. I. Malyuk, R. Maquil, R. G. Meuli, G. Mol, P. Negrel, P. O’Connor, R. K. Oorts, R. T. Ottesen, A. Pasieczna, W. Petersell, S. Pfleiderer, M. Poňavič, S. Pramuka, C. Prazeres, U. Rauch, S. Radusinović, M. Sadeghi, I. Salpeteur, R. Scanlon, A. Schedl, A. J. Scheib, I. Schoeters, P. Šefčik, E. Sellersjö, F. Skopljak, I. Slaninka, A. Šorša, R. Srvkota, T. Stafilov, T. Tarvainen, V. Trendavilov, P. Valera, V. Verougstraete, D. Vidojević, A. Zissimos, Z. Zomeni

^*Corresponding author for this work

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Abstract

Two thousand one hundred and eight agricultural soils (0–20 cm depth) collected at a density of one sample per 2500 km2 under the auspices of the Geochemical Mapping of Agricultural Soils (GEMAS) project over most of the European continent have been analysed using the Mobile Metal Ion (MMI®) partial extraction technique with ICP-MS finish. For a number of elements, notably Ce, Ni, and Ca, coherent geogenic patterns have been observed which relate to underlying lithology. For Fe and Al, coherent patterns are also observed but the effects of weathering are evident, and provide a mechanism to explain the acidity of soils in high rainfall areas. Individual anomalies, many related to anthropogenic activity (mining, metallurgy, agriculture) have been observed for Ag, Au, Cu, Pb, Cd and Zn. Comparison of the results with aqua regia digestion and the equivalent National Geochemistry Survey of Australia (NGSA) provides insights into weathering processes and the concept of bioavailability.

Original language	English
Pages (from-to)	99-112
Number of pages	14
Journal	Geochemistry: Exploration, Environment, Analysis
Volume	15
Issue number	2-3
DOIs	https://doi.org/10.1144/geochem2014-279
Publication status	Published - 13 Jul 2015

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10.1144/geochem2014-279

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Mann, A., Reimann, C., De Caritat, P., Turner, N., Birke, M., Albanese, S., Andersson, M., Baritz, R., Batista, M. J., Bel-Lan, A., Cicchella, D., Demetriades, A., De Vivo, B., De Vos, W., Dinelli, E., Ďuriš, M., Dusza-Dobek, A., Eggen, O. A., Eklund, M., ... Zomeni, Z. (2015). Mobile metal ion® analysis of european agricultural soils: Bioavailability, weathering, Geogenic patterns and anthropogenic anomalies. Geochemistry: Exploration, Environment, Analysis, 15(2-3), 99-112. https://doi.org/10.1144/geochem2014-279

@article{3e705ec9bb0e46a3adf59a13f7fc01ce,

title = "Mobile metal ion{\textregistered} analysis of european agricultural soils: Bioavailability, weathering, Geogenic patterns and anthropogenic anomalies",

abstract = "Two thousand one hundred and eight agricultural soils (0–20 cm depth) collected at a density of one sample per 2500 km2 under the auspices of the Geochemical Mapping of Agricultural Soils (GEMAS) project over most of the European continent have been analysed using the Mobile Metal Ion (MMI{\textregistered}) partial extraction technique with ICP-MS finish. For a number of elements, notably Ce, Ni, and Ca, coherent geogenic patterns have been observed which relate to underlying lithology. For Fe and Al, coherent patterns are also observed but the effects of weathering are evident, and provide a mechanism to explain the acidity of soils in high rainfall areas. Individual anomalies, many related to anthropogenic activity (mining, metallurgy, agriculture) have been observed for Ag, Au, Cu, Pb, Cd and Zn. Comparison of the results with aqua regia digestion and the equivalent National Geochemistry Survey of Australia (NGSA) provides insights into weathering processes and the concept of bioavailability.",

keywords = "Anthropogenic anomalies, Bioavailability, GEMAS, Geochemical mapping, Geogenic patterns, ICP-MS, MMI{\textregistered} extraction",

author = "A. Mann and C. Reimann and {De Caritat}, P. and N. Turner and M. Birke and S. Albanese and M. Andersson and R. Baritz and Batista, {M. J.} and A. Bel-Lan and D. Cicchella and A. Demetriades and {De Vivo}, B. and {De Vos}, W. and E. Dinelli and M. {\v D}uri{\v s} and A. Dusza-Dobek and Eggen, {O. A.} and M. Eklund and V. Ernstsen and K. Fabian and P. Filzmoser and D. Flight and S. Forrester and M. Fuchs and U. F{\"u}gedi and A. Gilucis and M. Gosar and V. Gregorauskiene and {De Groot}, W. and A. Gulan and J. Halami{\'c} and E. Haslinger and P. Hayoz and R. Hoffmann and J. Hoogewerff and H. Hrvatovic and S. Husnjak and L. Janik and G. Jordan and M. Kaminari and J. Kirby and J. Kivisilla and V. Klos and F. Krone and P. Kwe{\'c}ko and L. Kuti and A. Ladenberger and A. Lima and J. Locutura and Lucivjansky, {D. P.} and A. Mann and D. Mackovych and M. McLaughlin and Malyuk, {B. I.} and R. Maquil and Meuli, {R. G.} and G. Mol and P. Negrel and P. O{\textquoteright}Connor and Oorts, {R. K.} and Ottesen, {R. T.} and A. Pasieczna and W. Petersell and S. Pfleiderer and M. Po{\v n}avi{\v c} and S. Pramuka and C. Prazeres and U. Rauch and S. Radusinovi{\'c} and M. Sadeghi and I. Salpeteur and R. Scanlon and A. Schedl and Scheib, {A. J.} and I. Schoeters and P. {\v S}ef{\v c}ik and E. Sellersj{\"o} and F. Skopljak and I. Slaninka and A. {\v S}or{\v s}a and R. Srvkota and T. Stafilov and T. Tarvainen and V. Trendavilov and P. Valera and V. Verougstraete and D. Vidojevi{\'c} and A. Zissimos and Z. Zomeni",

note = "Publisher Copyright: {\textcopyright} 2015 AAG/The Geological Society of London.",

year = "2015",

month = jul,

day = "13",

doi = "10.1144/geochem2014-279",

language = "English",

volume = "15",

pages = "99--112",

journal = "Geochemistry: Exploration, Environment, Analysis",

issn = "1467-7873",

publisher = "Geological Society of London",

number = "2-3",

}

Mann, A, Reimann, C, De Caritat, P, Turner, N, Birke, M, Albanese, S, Andersson, M, Baritz, R, Batista, MJ, Bel-Lan, A, Cicchella, D, Demetriades, A, De Vivo, B, De Vos, W, Dinelli, E, Ďuriš, M, Dusza-Dobek, A, Eggen, OA, Eklund, M, Ernstsen, V, Fabian, K, Filzmoser, P, Flight, D, Forrester, S, Fuchs, M, Fügedi, U, Gilucis, A, Gosar, M, Gregorauskiene, V, De Groot, W, Gulan, A, Halamić, J, Haslinger, E, Hayoz, P, Hoffmann, R, Hoogewerff, J, Hrvatovic, H, Husnjak, S, Janik, L, Jordan, G, Kaminari, M, Kirby, J, Kivisilla, J, Klos, V, Krone, F, Kwećko, P, Kuti, L, Ladenberger, A, Lima, A, Locutura, J, Lucivjansky, DP, Mann, A, Mackovych, D, McLaughlin, M, Malyuk, BI, Maquil, R, Meuli, RG, Mol, G, Negrel, P, O’Connor, P, Oorts, RK, Ottesen, RT, Pasieczna, A, Petersell, W, Pfleiderer, S, Poňavič, M, Pramuka, S, Prazeres, C, Rauch, U, Radusinović, S, Sadeghi, M, Salpeteur, I, Scanlon, R, Schedl, A, Scheib, AJ, Schoeters, I, Šefčik, P, Sellersjö, E, Skopljak, F, Slaninka, I, Šorša, A, Srvkota, R, Stafilov, T, Tarvainen, T, Trendavilov, V, Valera, P, Verougstraete, V, Vidojević, D, Zissimos, A & Zomeni, Z 2015, 'Mobile metal ion® analysis of european agricultural soils: Bioavailability, weathering, Geogenic patterns and anthropogenic anomalies', Geochemistry: Exploration, Environment, Analysis, vol. 15, no. 2-3, pp. 99-112. https://doi.org/10.1144/geochem2014-279

TY - JOUR

T1 - Mobile metal ion® analysis of european agricultural soils

T2 - Bioavailability, weathering, Geogenic patterns and anthropogenic anomalies

AU - Mann, A.

AU - Reimann, C.

AU - De Caritat, P.

AU - Turner, N.

AU - Birke, M.

AU - Albanese, S.

AU - Andersson, M.

AU - Baritz, R.

AU - Batista, M. J.

AU - Bel-Lan, A.

AU - Cicchella, D.

AU - Demetriades, A.

AU - De Vivo, B.

AU - De Vos, W.

AU - Dinelli, E.

AU - Ďuriš, M.

AU - Dusza-Dobek, A.

AU - Eggen, O. A.

AU - Eklund, M.

AU - Ernstsen, V.

AU - Fabian, K.

AU - Filzmoser, P.

AU - Flight, D.

AU - Forrester, S.

AU - Fuchs, M.

AU - Fügedi, U.

AU - Gilucis, A.

AU - Gosar, M.

AU - Gregorauskiene, V.

AU - De Groot, W.

AU - Gulan, A.

AU - Halamić, J.

AU - Haslinger, E.

AU - Hayoz, P.

AU - Hoffmann, R.

AU - Hoogewerff, J.

AU - Hrvatovic, H.

AU - Husnjak, S.

AU - Janik, L.

AU - Jordan, G.

AU - Kaminari, M.

AU - Kirby, J.

AU - Kivisilla, J.

AU - Klos, V.

AU - Krone, F.

AU - Kwećko, P.

AU - Kuti, L.

AU - Ladenberger, A.

AU - Lima, A.

AU - Locutura, J.

AU - Lucivjansky, D. P.

AU - Mann, A.

AU - Mackovych, D.

AU - McLaughlin, M.

AU - Malyuk, B. I.

AU - Maquil, R.

AU - Meuli, R. G.

AU - Mol, G.

AU - Negrel, P.

AU - O’Connor, P.

AU - Oorts, R. K.

AU - Ottesen, R. T.

AU - Pasieczna, A.

AU - Petersell, W.

AU - Pfleiderer, S.

AU - Poňavič, M.

AU - Pramuka, S.

AU - Prazeres, C.

AU - Rauch, U.

AU - Radusinović, S.

AU - Sadeghi, M.

AU - Salpeteur, I.

AU - Scanlon, R.

AU - Schedl, A.

AU - Scheib, A. J.

AU - Schoeters, I.

AU - Šefčik, P.

AU - Sellersjö, E.

AU - Skopljak, F.

AU - Slaninka, I.

AU - Šorša, A.

AU - Srvkota, R.

AU - Stafilov, T.

AU - Tarvainen, T.

AU - Trendavilov, V.

AU - Valera, P.

AU - Verougstraete, V.

AU - Vidojević, D.

AU - Zissimos, A.

AU - Zomeni, Z.

PY - 2015/7/13

Y1 - 2015/7/13

N2 - Two thousand one hundred and eight agricultural soils (0–20 cm depth) collected at a density of one sample per 2500 km2 under the auspices of the Geochemical Mapping of Agricultural Soils (GEMAS) project over most of the European continent have been analysed using the Mobile Metal Ion (MMI®) partial extraction technique with ICP-MS finish. For a number of elements, notably Ce, Ni, and Ca, coherent geogenic patterns have been observed which relate to underlying lithology. For Fe and Al, coherent patterns are also observed but the effects of weathering are evident, and provide a mechanism to explain the acidity of soils in high rainfall areas. Individual anomalies, many related to anthropogenic activity (mining, metallurgy, agriculture) have been observed for Ag, Au, Cu, Pb, Cd and Zn. Comparison of the results with aqua regia digestion and the equivalent National Geochemistry Survey of Australia (NGSA) provides insights into weathering processes and the concept of bioavailability.

AB - Two thousand one hundred and eight agricultural soils (0–20 cm depth) collected at a density of one sample per 2500 km2 under the auspices of the Geochemical Mapping of Agricultural Soils (GEMAS) project over most of the European continent have been analysed using the Mobile Metal Ion (MMI®) partial extraction technique with ICP-MS finish. For a number of elements, notably Ce, Ni, and Ca, coherent geogenic patterns have been observed which relate to underlying lithology. For Fe and Al, coherent patterns are also observed but the effects of weathering are evident, and provide a mechanism to explain the acidity of soils in high rainfall areas. Individual anomalies, many related to anthropogenic activity (mining, metallurgy, agriculture) have been observed for Ag, Au, Cu, Pb, Cd and Zn. Comparison of the results with aqua regia digestion and the equivalent National Geochemistry Survey of Australia (NGSA) provides insights into weathering processes and the concept of bioavailability.

KW - Anthropogenic anomalies

KW - Bioavailability

KW - GEMAS

KW - Geochemical mapping

KW - Geogenic patterns

KW - ICP-MS

KW - MMI® extraction

UR - http://www.scopus.com/inward/record.url?scp=84938536382&partnerID=8YFLogxK

U2 - 10.1144/geochem2014-279

DO - 10.1144/geochem2014-279

M3 - Article

SN - 1467-7873

VL - 15

SP - 99

EP - 112

JO - Geochemistry: Exploration, Environment, Analysis

JF - Geochemistry: Exploration, Environment, Analysis

IS - 2-3

ER -

Mobile metal ion® analysis of european agricultural soils: Bioavailability, weathering, Geogenic patterns and anthropogenic anomalies

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