Mono- and trinuclear aroyl complexes of iron:: Crystal Structure of Hg[Fe{C(O)C6H3Me2-2,6}(CO)3(PPh3)]2

Stephen Anderson; Anthony F. Hill; Andrew J. P. White; David J. Williams

doi:10.1021/om971058y

Mono- and trinuclear aroyl complexes of iron: Crystal Structure of Hg[Fe{C(O)C6H3Me2-2,6}(CO)3(PPh3)]2

Stephen Anderson, Anthony F. Hill^*, Andrew J. P. White, David J. Williams

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of [Fe(CO)5] with LiR (R = C6H3Me2-2,6) provides [Fe{C(OLi)R}(CO)4], which reacts with I2 or HgCl2 in the presence of PPh3 to provide respectively [Fe(η2-OCR)I(CO)2(PPh3)] or Hg[Fe{C(O)R}(CO)3(PPh3)]2; the latter has been characterized by X-ray diffraction. The reaction of [Fe(η2-OCR)I(CO)2(PPh3)] with K[HB(pz)3] (pz = pyrazol-1-yl) leads to [Fe{C(O)R}(CO)2{HB(pz)3}] which is converted thermally to [Fe{HB(pz)3}2].

Original language	English
Pages (from-to)	2665-2668
Number of pages	4
Journal	Organometallics
Volume	17
Issue number	12
DOIs	https://doi.org/10.1021/om971058y
Publication status	Published - 8 May 1998
Externally published	Yes

Access to Document

10.1021/om971058y

Cite this

@article{e2d43af266984cd2a28f3bc4ad5d7638,

title = "Mono- and trinuclear aroyl complexes of iron:: Crystal Structure of Hg[Fe\{C(O)C6H3Me2-2,6\}(CO)3(PPh3)]2",

abstract = "The reaction of [Fe(CO)5] with LiR (R = C6H3Me2-2,6) provides [Fe\{C(OLi)R\}(CO)4], which reacts with I2 or HgCl2 in the presence of PPh3 to provide respectively [Fe(η2-OCR)I(CO)2(PPh3)] or Hg[Fe\{C(O)R\}(CO)3(PPh3)]2; the latter has been characterized by X-ray diffraction. The reaction of [Fe(η2-OCR)I(CO)2(PPh3)] with K[HB(pz)3] (pz = pyrazol-1-yl) leads to [Fe\{C(O)R\}(CO)2\{HB(pz)3\}] which is converted thermally to [Fe\{HB(pz)3\}2].",

keywords = "= zn, Hg, Fe, Cd",

author = "Stephen Anderson and Hill, \{Anthony F.\} and White, \{Andrew J. P.\} and Williams, \{David J.\}",

year = "1998",

month = may,

day = "8",

doi = "10.1021/om971058y",

language = "English",

volume = "17",

pages = "2665--2668",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "12",

}

TY - JOUR

T1 - Mono- and trinuclear aroyl complexes of iron:

T2 - Crystal Structure of Hg[Fe{C(O)C6H3Me2-2,6}(CO)3(PPh3)]2

AU - Anderson, Stephen

AU - Hill, Anthony F.

AU - White, Andrew J. P.

AU - Williams, David J.

PY - 1998/5/8

Y1 - 1998/5/8

N2 - The reaction of [Fe(CO)5] with LiR (R = C6H3Me2-2,6) provides [Fe{C(OLi)R}(CO)4], which reacts with I2 or HgCl2 in the presence of PPh3 to provide respectively [Fe(η2-OCR)I(CO)2(PPh3)] or Hg[Fe{C(O)R}(CO)3(PPh3)]2; the latter has been characterized by X-ray diffraction. The reaction of [Fe(η2-OCR)I(CO)2(PPh3)] with K[HB(pz)3] (pz = pyrazol-1-yl) leads to [Fe{C(O)R}(CO)2{HB(pz)3}] which is converted thermally to [Fe{HB(pz)3}2].

AB - The reaction of [Fe(CO)5] with LiR (R = C6H3Me2-2,6) provides [Fe{C(OLi)R}(CO)4], which reacts with I2 or HgCl2 in the presence of PPh3 to provide respectively [Fe(η2-OCR)I(CO)2(PPh3)] or Hg[Fe{C(O)R}(CO)3(PPh3)]2; the latter has been characterized by X-ray diffraction. The reaction of [Fe(η2-OCR)I(CO)2(PPh3)] with K[HB(pz)3] (pz = pyrazol-1-yl) leads to [Fe{C(O)R}(CO)2{HB(pz)3}] which is converted thermally to [Fe{HB(pz)3}2].

KW - = zn

KW - Hg

KW - Fe

KW - Cd

UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:000074172700039&DestLinkType=FullRecord&DestApp=WOS_CPL

U2 - 10.1021/om971058y

DO - 10.1021/om971058y

M3 - Article

SN - 0276-7333

VL - 17

SP - 2665

EP - 2668

JO - Organometallics

JF - Organometallics

IS - 12

ER -

Mono- and trinuclear aroyl complexes of iron: Crystal Structure of Hg[Fe{C(O)C6H3Me2-2,6}(CO)3(PPh3)]2

Abstract

Access to Document

Other files and links

Fingerprint

Cite this