Nano-Powdered Calcium Carbonate Reference Materials: Significant Progress for Microanalysis?

Klaus Peter Jochum; Dieter Garbe-Schönberg; Marina Veter; Brigitte Stoll; Ulrike Weis; Michael Weber; Federico Lugli; Anna Jentzen; Ralf Schiebel; Jasper A. Wassenburg; Dorrit E. Jacob; Gerald H. Haug

doi:10.1111/ggr.12292

Nano-Powdered Calcium Carbonate Reference Materials: Significant Progress for Microanalysis?

Klaus Peter Jochum^*, Dieter Garbe-Schönberg, Marina Veter, Brigitte Stoll, Ulrike Weis, Michael Weber, Federico Lugli, Anna Jentzen, Ralf Schiebel, Jasper A. Wassenburg, Dorrit E. Jacob, Gerald H. Haug

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

68 Citations (Scopus)

Abstract

Homogeneity, mass fractions of about forty trace elements and Sr isotope composition of Ca carbonate reference materials (RMs) between original and nano-powdered pellets are compared. Our results using nanosecond and femtosecond LA-(MC)-ICP-MS show that the nano-pellets of the RMs MACS-3NP, JCp-1NP and JCt-1NP are about a factor of 2–3 more homogeneous than the original samples MACS-3, JCp-1 and JCt-1, and are therefore much more suitable for microanalytical purposes. With the exception of Si, the mass fractions of the synthetic RM MACS-3 agree with its fine-grained analogue MACS-3NP. Very small, but significant, differences between original and nano-pellets are observed in the RMs JCp-1 and JCt-1 for some trace elements with very low contents, indicating the need for re-certification. Strontium mass fractions in the analysed RMs are high (1500–7000 mg kg⁻¹), and their isotope compositions determined by LA-MC-ICP-MS in the original and the nano-pellets agree within uncertainty limits.

Original language	English
Pages (from-to)	595-609
Number of pages	15
Journal	Geostandards and Geoanalytical Research
Volume	43
Issue number	4
DOIs	https://doi.org/10.1111/ggr.12292
Publication status	Published - 1 Dec 2019
Externally published	Yes

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@article{976558c33c8b4208ba335f471e73fd34,

title = "Nano-Powdered Calcium Carbonate Reference Materials: Significant Progress for Microanalysis?",

abstract = "Homogeneity, mass fractions of about forty trace elements and Sr isotope composition of Ca carbonate reference materials (RMs) between original and nano-powdered pellets are compared. Our results using nanosecond and femtosecond LA-(MC)-ICP-MS show that the nano-pellets of the RMs MACS-3NP, JCp-1NP and JCt-1NP are about a factor of 2–3 more homogeneous than the original samples MACS-3, JCp-1 and JCt-1, and are therefore much more suitable for microanalytical purposes. With the exception of Si, the mass fractions of the synthetic RM MACS-3 agree with its fine-grained analogue MACS-3NP. Very small, but significant, differences between original and nano-pellets are observed in the RMs JCp-1 and JCt-1 for some trace elements with very low contents, indicating the need for re-certification. Strontium mass fractions in the analysed RMs are high (1500–7000 mg kg−1), and their isotope compositions determined by LA-MC-ICP-MS in the original and the nano-pellets agree within uncertainty limits.",

keywords = "carbonate, homogeneity, laser ablation-inductively coupled plasma-mass spectrometry, microanalysis, reference materials",

author = "Jochum, \{Klaus Peter\} and Dieter Garbe-Sch{\"o}nberg and Marina Veter and Brigitte Stoll and Ulrike Weis and Michael Weber and Federico Lugli and Anna Jentzen and Ralf Schiebel and Wassenburg, \{Jasper A.\} and Jacob, \{Dorrit E.\} and Haug, \{Gerald H.\}",

note = "Publisher Copyright: {\textcopyright} 2019 The Authors. Geostandards and Geoanalytical Research published by John Wiley \& Sons Ltd on behalf of International Association of Geoanalysts",

year = "2019",

month = dec,

day = "1",

doi = "10.1111/ggr.12292",

language = "English",

volume = "43",

pages = "595--609",

journal = "Geostandards and Geoanalytical Research",

issn = "1639-4488",

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TY - JOUR

T1 - Nano-Powdered Calcium Carbonate Reference Materials

T2 - Significant Progress for Microanalysis?

AU - Jochum, Klaus Peter

AU - Garbe-Schönberg, Dieter

AU - Veter, Marina

AU - Stoll, Brigitte

AU - Weis, Ulrike

AU - Weber, Michael

AU - Lugli, Federico

AU - Jentzen, Anna

AU - Schiebel, Ralf

AU - Wassenburg, Jasper A.

AU - Jacob, Dorrit E.

AU - Haug, Gerald H.

PY - 2019/12/1

Y1 - 2019/12/1

N2 - Homogeneity, mass fractions of about forty trace elements and Sr isotope composition of Ca carbonate reference materials (RMs) between original and nano-powdered pellets are compared. Our results using nanosecond and femtosecond LA-(MC)-ICP-MS show that the nano-pellets of the RMs MACS-3NP, JCp-1NP and JCt-1NP are about a factor of 2–3 more homogeneous than the original samples MACS-3, JCp-1 and JCt-1, and are therefore much more suitable for microanalytical purposes. With the exception of Si, the mass fractions of the synthetic RM MACS-3 agree with its fine-grained analogue MACS-3NP. Very small, but significant, differences between original and nano-pellets are observed in the RMs JCp-1 and JCt-1 for some trace elements with very low contents, indicating the need for re-certification. Strontium mass fractions in the analysed RMs are high (1500–7000 mg kg−1), and their isotope compositions determined by LA-MC-ICP-MS in the original and the nano-pellets agree within uncertainty limits.

AB - Homogeneity, mass fractions of about forty trace elements and Sr isotope composition of Ca carbonate reference materials (RMs) between original and nano-powdered pellets are compared. Our results using nanosecond and femtosecond LA-(MC)-ICP-MS show that the nano-pellets of the RMs MACS-3NP, JCp-1NP and JCt-1NP are about a factor of 2–3 more homogeneous than the original samples MACS-3, JCp-1 and JCt-1, and are therefore much more suitable for microanalytical purposes. With the exception of Si, the mass fractions of the synthetic RM MACS-3 agree with its fine-grained analogue MACS-3NP. Very small, but significant, differences between original and nano-pellets are observed in the RMs JCp-1 and JCt-1 for some trace elements with very low contents, indicating the need for re-certification. Strontium mass fractions in the analysed RMs are high (1500–7000 mg kg−1), and their isotope compositions determined by LA-MC-ICP-MS in the original and the nano-pellets agree within uncertainty limits.

KW - carbonate

KW - homogeneity

KW - laser ablation-inductively coupled plasma-mass spectrometry

KW - microanalysis

KW - reference materials

UR - https://www.scopus.com/pages/publications/85071872512

U2 - 10.1111/ggr.12292

DO - 10.1111/ggr.12292

M3 - Article

SN - 1639-4488

VL - 43

SP - 595

EP - 609

JO - Geostandards and Geoanalytical Research

JF - Geostandards and Geoanalytical Research

IS - 4

ER -

Nano-Powdered Calcium Carbonate Reference Materials: Significant Progress for Microanalysis?

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