Near linear Ta-H-B geometry: [TaCl2(η-C5Me 5){Κ3-H,S,S′-H2B(methimazolyl)2}]

Anthony F. Hill; Matthew K. Smith; Jörg Wagler

doi:10.1021/om7008099

Near linear Ta-H-B geometry: [TaCl₂(η-C₅Me ₅){Κ³-H,S,S′-H₂B(methimazolyl)2}]

Anthony F. Hill, Matthew K. Smith, Jörg Wagler

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

The reaction of [TaCl₄(η-C₅Me₅)] with Na[H₂B(mt)₂] provides the tantalum(IV) complex [TaCl ₂(η-C₅Me₅){H₂B(mt) ₂}], the crystal structure of which reveals an essentially linear Ta-H-B interaction.

Original language	English
Pages (from-to)	2137-2140
Number of pages	4
Journal	Organometallics
Volume	27
Issue number	9
DOIs	https://doi.org/10.1021/om7008099
Publication status	Published - 12 May 2008

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title = "Near linear Ta-H-B geometry: [TaCl2(η-C5Me 5){Κ3-H,S,S′-H2B(methimazolyl)2}]",

abstract = "The reaction of [TaCl4(η-C5Me5)] with Na[H2B(mt)2] provides the tantalum(IV) complex [TaCl 2(η-C5Me5){H2B(mt) 2}], the crystal structure of which reveals an essentially linear Ta-H-B interaction.",

author = "Hill, {Anthony F.} and Smith, {Matthew K.} and J{\"o}rg Wagler",

year = "2008",

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language = "English",

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journal = "Organometallics",

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T2 - [TaCl2(η-C5Me 5){Κ3-H,S,S′-H2B(methimazolyl)2}]

AU - Hill, Anthony F.

AU - Smith, Matthew K.

AU - Wagler, Jörg

PY - 2008/5/12

Y1 - 2008/5/12

N2 - The reaction of [TaCl4(η-C5Me5)] with Na[H2B(mt)2] provides the tantalum(IV) complex [TaCl 2(η-C5Me5){H2B(mt) 2}], the crystal structure of which reveals an essentially linear Ta-H-B interaction.

AB - The reaction of [TaCl4(η-C5Me5)] with Na[H2B(mt)2] provides the tantalum(IV) complex [TaCl 2(η-C5Me5){H2B(mt) 2}], the crystal structure of which reveals an essentially linear Ta-H-B interaction.

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U2 - 10.1021/om7008099

DO - 10.1021/om7008099

M3 - Article

SN - 0276-7333

VL - 27

SP - 2137

EP - 2140

JO - Organometallics

JF - Organometallics

IS - 9

ER -

Near linear Ta-H-B geometry: [TaCl₂(η-C₅Me ₅){Κ³-H,S,S′-H₂B(methimazolyl)2}]

Abstract

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